亚硫酰氯(CAS 7719-09-7):分子式 Cl2OS、分子量 118.97;类别 医药中间体。
| CAS号 | 7719-09-7 |
|---|---|
| 分子式 | Cl2OS |
| 分子量 | 118.97 |
| 熔点 | -156 °F (NIOSH, 2024) |
| 沸点 | 169 °F at 760 mmHg (NIOSH, 2024) |
| LogP | 1.5 |
| 应用领域 | Uses: Used to make herbicides、drugs、dyes、and plastics、Also used as an electrolyte in lithium batteries、[ACGIH]、Battery Manufacturing [Category: Industry]、Toxic Gas from Spilling Chemical in Water [Category: Other]、For making acyl chlorides、to replace、hydroxide or sulfhydryl、groups with chlorine atoms、reacts with Grignard reagents to form the corresponding sulfoxides.、... Used to make acyl chlorides and to synthesize pharmaceuticals including drugs and vitamins. It is used to make dyes、to prepare organic chlorine compounds、as a solvent in the production of herbicides、and as an electrolyte in lithium batteries. Thionyl chloride is also used to prepare polyarylate-type engineering thermoplastics made from iso- and tere-phthaloyl chlorides.、Manufacture of、pesticides、engineering plastics、chlorinating agent、catalyst、Required in the manufacture of methylphosphonic dichloride、a key precursor for the nerve gas Sarin.、In the synthesis of various nerve agents、Methods of Manufacturing: Thionyl chloride is now generally produced by treating SO2 or SO3 with SCl2 at ca. 150-250 °C in the presence of activated carbon. The crude product is purified by distillation after addition of sulfur. Crude thionyl chloride production is a continuous process、but the distillation is carried out either continuously or in batches. The side product SO2 can be reacted with chlorine to give SO2Cl2 and thus recycled. ... Technical-grade thionyl chloride can contain sulfur chlorides、SO2、and SO2Cl2. Sulfur chlorides can be removed by distillation over sulfur、in some cases with the addition of FeCl3 or AlCl3. For laboratory-scale purification、distillation with triphenyl phosphite or dipentene is recommended. Modern processes give thionyl chloride in a quality which does not require any additional purification.、Prepared by the oxidation of sulfur dichloride with sulfur trioxide ... .、Edwards、United States patent 2362057 (1944 to Hooker Electrochemical) ... .、Impurities: The following impurities can be present: <、= 0.3% SO2、<、= 0.2% SO2Cl2、= 0.05% sulfur chlorides、and <、= 0.1% evaporation residue.、Formulations、Preparations: Technical-grade ... The thionyl chloride content should be min. 99.6%.、Grade: 93%、97.5%、U.S. Production: (1972) GREATER THAN 4.54X10+5 GRAMS、(1975) GREATER THAN 4.54X10+5 GRAMS、Production volumes for non-confidential chemicals reported under the Inventory Update Rule. [Table#2291]、Non-confidential 2016 Chemical Data Reporting (CDR) information on the production and use of chemicals manufactured or imported into the United States. Chemical: Thionyl chloride:、Table: National Aggregate Production Volume (pounds) [Table#2292]、General Manufacturing Information: Thionyl chloride: ACTIVE、The Chemical Weapons Convention (CWC) is an international treaty which bans the development、production、stockpiling、and transfer or use of chemical weapons. The Convention mandates the destruction and prohibition of chemical weapons and related facilities and provides for restrictions on international trade in toxic chemicals and precursors.、The Convention's monitoring and verification measures involve submission of declarations regarding ...、Schedule 1、2、and 3 chemicals、and inspections by the Organization for the Prohibition of Chemical Weapons of the facilities where these chemicals are produced. ... Schedule 3 chemicals ...、may、have been stockpiled or used as weapons、but ... are produced、and used、in large quantities for purposes not prohibited by the Convention (2). Thionyl chloride is listed in the CWC Annex on Chemicals under Schedule 3 (1). |
| 类别 | 医药中间体 |
登记用途:Uses: Used to make herbicides、drugs、dyes、and plastics、Also used as an electrolyte in lithium batteries、[ACGIH]、Battery Manufacturing [Category: Industry]、Toxic Gas from Spilling Chemical in Water [Category: Other]、For making acyl chlorides、to replace、hydroxide or sulfhydryl、groups with chlorine atoms、reacts with Grignard reagents to form the corresponding sulfoxides.、... Used to make acyl chlorides and to synthesize pharmaceuticals including drugs and vitamins. It is used to make dyes、to prepare organic chlorine compounds、as a solvent in the production of herbicides、and as an electrolyte in lithium batteries. Thionyl chloride is also used to prepare polyarylate-type engineering thermoplastics made from iso- and tere-phthaloyl chlorides.、Manufacture of、pesticides、engineering plastics、chlorinating agent、catalyst、Required in the manufacture of methylphosphonic dichloride、a key precursor for the nerve gas Sarin.、In the synthesis of various nerve agents、Methods of Manufacturing: Thionyl chloride is now generally produced by treating SO2 or SO3 with SCl2 at ca. 150-250 °C in the presence of activated carbon. The crude product is purified by distillation after addition of sulfur. Crude thionyl chloride production is a continuous process、but the distillation is carried out either continuously or in batches. The side product SO2 can be reacted with chlorine to give SO2Cl2 and thus recycled. ... Technical-grade thionyl chloride can contain sulfur chlorides、SO2、and SO2Cl2. Sulfur chlorides can be removed by distillation over sulfur、in some cases with the addition of FeCl3 or AlCl3. For laboratory-scale purification、distillation with triphenyl phosphite or dipentene is recommended. Modern processes give thionyl chloride in a quality which does not require any additional purification.、Prepared by the oxidation of sulfur dichloride with sulfur trioxide ... .、Edwards、United States patent 2362057 (1944 to Hooker Electrochemical) ... .、Impurities: The following impurities can be present: <、= 0.3% SO2、<、= 0.2% SO2Cl2、= 0.05% sulfur chlorides、and <、= 0.1% evaporation residue.、Formulations、Preparations: Technical-grade ... The thionyl chloride content should be min. 99.6%.、Grade: 93%、97.5%、U.S. Production: (1972) GREATER THAN 4.54X10+5 GRAMS、(1975) GREATER THAN 4.54X10+5 GRAMS、Production volumes for non-confidential chemicals reported under the Inventory Update Rule. [Table#2291]、Non-confidential 2016 Chemical Data Reporting (CDR) information on the production and use of chemicals manufactured or imported into the United States. Chemical: Thionyl chloride:、Table: National Aggregate Production Volume (pounds) [Table#2292]、General Manufacturing Information: Thionyl chloride: ACTIVE、The Chemical Weapons Convention (CWC) is an international treaty which bans the development、production、stockpiling、and transfer or use of chemical weapons. The Convention mandates the destruction and prohibition of chemical weapons and related facilities and provides for restrictions on international trade in toxic chemicals and precursors.、The Convention's monitoring and verification measures involve submission of declarations regarding ...、Schedule 1、2、and 3 chemicals、and inspections by the Organization for the Prohibition of Chemical Weapons of the facilities where these chemicals are produced. ... Schedule 3 chemicals ...、may、have been stockpiled or used as weapons、but ... are produced、and used、in large quantities for purposes not prohibited by the Convention (2). Thionyl chloride is listed in the CWC Annex on Chemicals under Schedule 3 (1).。
亚硫酰氯 是一种化工化合物,登记 CAS 号为 7719-09-7,分子式 Cl2OS(分子量 118.97),归属于医药中间体大类化工原料。
登记 CAS 号:7719-09-7
其分子式 Cl2OS 由 2 个氯、1 个氧、1 个硫 组成。
别名/同义词:亚硫酰氯 · Thionyl Chloride
所属分类:医药中间体
亚硫酰氯 的 CAS 登记号为 7719-09-7。
分子式 Cl2OS,分子量 118.97。
别名/同义词:亚硫酰氯、Thionyl Chloride。
登记用途:Uses: Used to make herbicides、drugs、dyes、and plastics、Also used as an electrolyte in lithium batteries、[ACGIH]、Battery Manufacturing [Category: Industry]、Toxic Gas from Spilling Chemical in Water [Category: Other]、For making acyl chlorides、to replace、hydroxide or sulfhydryl、groups with chlorine atoms、reacts with Grignard reagents to form the corresponding sulfoxides.、... Used to make acyl chlorides and to synthesize pharmaceuticals including drugs and vitamins. It is used to make dyes、to prepare organic chlorine compounds、as a solvent in the production of herbicides、and as an electrolyte in lithium batteries. Thionyl chloride is also used to prepare polyarylate-type engineering thermoplastics made from iso- and tere-phthaloyl chlorides.、Manufacture of、pesticides、engineering plastics、chlorinating agent、catalyst、Required in the manufacture of methylphosphonic dichloride、a key precursor for the nerve gas Sarin.、In the synthesis of various nerve agents、Methods of Manufacturing: Thionyl chloride is now generally produced by treating SO2 or SO3 with SCl2 at ca. 150-250 °C in the presence of activated carbon. The crude product is purified by distillation after addition of sulfur. Crude thionyl chloride production is a continuous process、but the distillation is carried out either continuously or in batches. The side product SO2 can be reacted with chlorine to give SO2Cl2 and thus recycled. ... Technical-grade thionyl chloride can contain sulfur chlorides、SO2、and SO2Cl2. Sulfur chlorides can be removed by distillation over sulfur、in some cases with the addition of FeCl3 or AlCl3. For laboratory-scale purification、distillation with triphenyl phosphite or dipentene is recommended. Modern processes give thionyl chloride in a quality which does not require any additional purification.、Prepared by the oxidation of sulfur dichloride with sulfur trioxide ... .、Edwards、United States patent 2362057 (1944 to Hooker Electrochemical) ... .、Impurities: The following impurities can be present: <、= 0.3% SO2、<、= 0.2% SO2Cl2、= 0.05% sulfur chlorides、and <、= 0.1% evaporation residue.、Formulations、Preparations: Technical-grade ... The thionyl chloride content should be min. 99.6%.、Grade: 93%、97.5%、U.S. Production: (1972) GREATER THAN 4.54X10+5 GRAMS、(1975) GREATER THAN 4.54X10+5 GRAMS、Production volumes for non-confidential chemicals reported under the Inventory Update Rule. [Table#2291]、Non-confidential 2016 Chemical Data Reporting (CDR) information on the production and use of chemicals manufactured or imported into the United States. Chemical: Thionyl chloride:、Table: National Aggregate Production Volume (pounds) [Table#2292]、General Manufacturing Information: Thionyl chloride: ACTIVE、The Chemical Weapons Convention (CWC) is an international treaty which bans the development、production、stockpiling、and transfer or use of chemical weapons. The Convention mandates the destruction and prohibition of chemical weapons and related facilities and provides for restrictions on international trade in toxic chemicals and precursors.、The Convention's monitoring and verification measures involve submission of declarations regarding ...、Schedule 1、2、and 3 chemicals、and inspections by the Organization for the Prohibition of Chemical Weapons of the facilities where these chemicals are produced. ... Schedule 3 chemicals ...、may、have been stockpiled or used as weapons、but ... are produced、and used、in large quantities for purposes not prohibited by the Convention (2). Thionyl chloride is listed in the CWC Annex on Chemicals under Schedule 3 (1).。
所属分类:医药中间体。
亚硫酰氯(CAS 7719-09-7)的独立参考数据,整理自公开化学数据库。
| CAS Registry Number | 7719-09-7 |
|---|---|
| PubChem CID | 24386 |
| Molecular formula | Cl2OS |
| IUPAC name | thionyl dichloride |
| UNII (FDA) | 4A8YJA13N4 |
| Molecular Weight | 118.97 |
|---|---|
| XLogP3 | 1.5 |
| Hydrogen Bond Donor Count | 0 |
| Hydrogen Bond Acceptor Count | 2 |
| Rotatable Bond Count | 0 |
| Exact Mass | 117.9046912 |
| Monoisotopic Mass | 117.9046912 |
| Topological Polar Surface Area | 36.3 |
| Heavy Atom Count | 4 |
| Boiling Point | 169 °F at 760 mmHg (NIOSH, 2024) |
|---|---|
| Boiling Point | 76 °C at 760 mm Hg |
| Boiling Point | 76 °C |
| Boiling Point | 169 °F |
| Boiling Point | 78.8 °C @760 [mm Hg] |
| Melting Point | -156 °F (NIOSH, 2024) |
| Melting Point | -104.5 °C |
| Melting Point | -156 °F |
| Melting Point | -105 °C |
| Density | 1.676 at 0 °C/4 °C; 1.655 at 10 °C/4 °C; 1.638 at 20 °C/4 °C |
THIONYL CHLORIDE; Thionyl dichloride; 7719-09-7; Sulfinyl chloride; Sulfurous dichloride; Sulfurous oxychloride; Sulfinyl dichloride; Sulfur oxychloride; Sulfur chloride oxide; Sulfur chloride oxide (Cl2SO); 4A8YJA13N4; DTXSID3064778; CHEBI:29290; RefChem:6303; DTXCID0047953; 231-748-8
| Reported hazard statements | H302, H314, H332, H318 (29.4%), H331 (45.7%), H335 (38.4%), H315 (100%), H319 (100%) |
|---|
H302: Harmful if swallowed [Warning Acute toxicity, oral]
H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
Thionyl Chloride · CAS 7719-09-7 · Cl2OS. UNII 4A8YJA13N4. Boiling Point: 169 °F at 760 mmHg (NIOSH, 2024); Boiling Point: 76 °C at 760 mm Hg; Boiling Point: 76 °C.
数据来源:PubChem / Wikidata;与随货 COA 不一致时以 COA 为准。
English page: Thionyl Chloride