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亚硫酰氯

CAS 7719-09-7Cl2OSMW 118.97

亚硫酰氯(CAS 7719-09-7):分子式 Cl2OS、分子量 118.97;类别 医药中间体。

产品概览

CAS号7719-09-7
分子式Cl2OS
分子量118.97
熔点-156 °F (NIOSH, 2024)
沸点169 °F at 760 mmHg (NIOSH, 2024)
LogP1.5
应用领域Uses: Used to make herbicides、drugs、dyes、and plastics、Also used as an electrolyte in lithium batteries、[ACGIH]、Battery Manufacturing [Category: Industry]、Toxic Gas from Spilling Chemical in Water [Category: Other]、For making acyl chlorides、to replace、hydroxide or sulfhydryl、groups with chlorine atoms、reacts with Grignard reagents to form the corresponding sulfoxides.、... Used to make acyl chlorides and to synthesize pharmaceuticals including drugs and vitamins. It is used to make dyes、to prepare organic chlorine compounds、as a solvent in the production of herbicides、and as an electrolyte in lithium batteries. Thionyl chloride is also used to prepare polyarylate-type engineering thermoplastics made from iso- and tere-phthaloyl chlorides.、Manufacture of、pesticides、engineering plastics、chlorinating agent、catalyst、Required in the manufacture of methylphosphonic dichloride、a key precursor for the nerve gas Sarin.、In the synthesis of various nerve agents、Methods of Manufacturing: Thionyl chloride is now generally produced by treating SO2 or SO3 with SCl2 at ca. 150-250 °C in the presence of activated carbon. The crude product is purified by distillation after addition of sulfur. Crude thionyl chloride production is a continuous process、but the distillation is carried out either continuously or in batches. The side product SO2 can be reacted with chlorine to give SO2Cl2 and thus recycled. ... Technical-grade thionyl chloride can contain sulfur chlorides、SO2、and SO2Cl2. Sulfur chlorides can be removed by distillation over sulfur、in some cases with the addition of FeCl3 or AlCl3. For laboratory-scale purification、distillation with triphenyl phosphite or dipentene is recommended. Modern processes give thionyl chloride in a quality which does not require any additional purification.、Prepared by the oxidation of sulfur dichloride with sulfur trioxide ... .、Edwards、United States patent 2362057 (1944 to Hooker Electrochemical) ... .、Impurities: The following impurities can be present: <、= 0.3% SO2、<、= 0.2% SO2Cl2、= 0.05% sulfur chlorides、and <、= 0.1% evaporation residue.、Formulations、Preparations: Technical-grade ... The thionyl chloride content should be min. 99.6%.、Grade: 93%、97.5%、U.S. Production: (1972) GREATER THAN 4.54X10+5 GRAMS、(1975) GREATER THAN 4.54X10+5 GRAMS、Production volumes for non-confidential chemicals reported under the Inventory Update Rule. [Table#2291]、Non-confidential 2016 Chemical Data Reporting (CDR) information on the production and use of chemicals manufactured or imported into the United States. Chemical: Thionyl chloride:、Table: National Aggregate Production Volume (pounds) [Table#2292]、General Manufacturing Information: Thionyl chloride: ACTIVE、The Chemical Weapons Convention (CWC) is an international treaty which bans the development、production、stockpiling、and transfer or use of chemical weapons. The Convention mandates the destruction and prohibition of chemical weapons and related facilities and provides for restrictions on international trade in toxic chemicals and precursors.、The Convention's monitoring and verification measures involve submission of declarations regarding ...、Schedule 1、2、and 3 chemicals、and inspections by the Organization for the Prohibition of Chemical Weapons of the facilities where these chemicals are produced. ... Schedule 3 chemicals ...、may、have been stockpiled or used as weapons、but ... are produced、and used、in large quantities for purposes not prohibited by the Convention (2). Thionyl chloride is listed in the CWC Annex on Chemicals under Schedule 3 (1).
类别医药中间体

应用领域

登记用途:Uses: Used to make herbicides、drugs、dyes、and plastics、Also used as an electrolyte in lithium batteries、[ACGIH]、Battery Manufacturing [Category: Industry]、Toxic Gas from Spilling Chemical in Water [Category: Other]、For making acyl chlorides、to replace、hydroxide or sulfhydryl、groups with chlorine atoms、reacts with Grignard reagents to form the corresponding sulfoxides.、... Used to make acyl chlorides and to synthesize pharmaceuticals including drugs and vitamins. It is used to make dyes、to prepare organic chlorine compounds、as a solvent in the production of herbicides、and as an electrolyte in lithium batteries. Thionyl chloride is also used to prepare polyarylate-type engineering thermoplastics made from iso- and tere-phthaloyl chlorides.、Manufacture of、pesticides、engineering plastics、chlorinating agent、catalyst、Required in the manufacture of methylphosphonic dichloride、a key precursor for the nerve gas Sarin.、In the synthesis of various nerve agents、Methods of Manufacturing: Thionyl chloride is now generally produced by treating SO2 or SO3 with SCl2 at ca. 150-250 °C in the presence of activated carbon. The crude product is purified by distillation after addition of sulfur. Crude thionyl chloride production is a continuous process、but the distillation is carried out either continuously or in batches. The side product SO2 can be reacted with chlorine to give SO2Cl2 and thus recycled. ... Technical-grade thionyl chloride can contain sulfur chlorides、SO2、and SO2Cl2. Sulfur chlorides can be removed by distillation over sulfur、in some cases with the addition of FeCl3 or AlCl3. For laboratory-scale purification、distillation with triphenyl phosphite or dipentene is recommended. Modern processes give thionyl chloride in a quality which does not require any additional purification.、Prepared by the oxidation of sulfur dichloride with sulfur trioxide ... .、Edwards、United States patent 2362057 (1944 to Hooker Electrochemical) ... .、Impurities: The following impurities can be present: <、= 0.3% SO2、<、= 0.2% SO2Cl2、= 0.05% sulfur chlorides、and <、= 0.1% evaporation residue.、Formulations、Preparations: Technical-grade ... The thionyl chloride content should be min. 99.6%.、Grade: 93%、97.5%、U.S. Production: (1972) GREATER THAN 4.54X10+5 GRAMS、(1975) GREATER THAN 4.54X10+5 GRAMS、Production volumes for non-confidential chemicals reported under the Inventory Update Rule. [Table#2291]、Non-confidential 2016 Chemical Data Reporting (CDR) information on the production and use of chemicals manufactured or imported into the United States. Chemical: Thionyl chloride:、Table: National Aggregate Production Volume (pounds) [Table#2292]、General Manufacturing Information: Thionyl chloride: ACTIVE、The Chemical Weapons Convention (CWC) is an international treaty which bans the development、production、stockpiling、and transfer or use of chemical weapons. The Convention mandates the destruction and prohibition of chemical weapons and related facilities and provides for restrictions on international trade in toxic chemicals and precursors.、The Convention's monitoring and verification measures involve submission of declarations regarding ...、Schedule 1、2、and 3 chemicals、and inspections by the Organization for the Prohibition of Chemical Weapons of the facilities where these chemicals are produced. ... Schedule 3 chemicals ...、may、have been stockpiled or used as weapons、but ... are produced、and used、in large quantities for purposes not prohibited by the Convention (2). Thionyl chloride is listed in the CWC Annex on Chemicals under Schedule 3 (1).。

技术档案

这个产品是什么

亚硫酰氯 是一种化工化合物,登记 CAS 号为 7719-09-7,分子式 Cl2OS(分子量 118.97),归属于医药中间体大类化工原料。

识别信息

登记 CAS 号:7719-09-7

其分子式 Cl2OS 由 2 个氯、1 个氧、1 个硫 组成。

别名/同义词:亚硫酰氯 · Thionyl Chloride

所属分类:医药中间体

常见问题

亚硫酰氯 的 CAS 号是多少?

亚硫酰氯 的 CAS 登记号为 7719-09-7。

亚硫酰氯 的分子式与分子量是多少?

分子式 Cl2OS,分子量 118.97。

亚硫酰氯 还有哪些别名?

别名/同义词:亚硫酰氯、Thionyl Chloride。

亚硫酰氯 的登记用途是什么?

登记用途:Uses: Used to make herbicides、drugs、dyes、and plastics、Also used as an electrolyte in lithium batteries、[ACGIH]、Battery Manufacturing [Category: Industry]、Toxic Gas from Spilling Chemical in Water [Category: Other]、For making acyl chlorides、to replace、hydroxide or sulfhydryl、groups with chlorine atoms、reacts with Grignard reagents to form the corresponding sulfoxides.、... Used to make acyl chlorides and to synthesize pharmaceuticals including drugs and vitamins. It is used to make dyes、to prepare organic chlorine compounds、as a solvent in the production of herbicides、and as an electrolyte in lithium batteries. Thionyl chloride is also used to prepare polyarylate-type engineering thermoplastics made from iso- and tere-phthaloyl chlorides.、Manufacture of、pesticides、engineering plastics、chlorinating agent、catalyst、Required in the manufacture of methylphosphonic dichloride、a key precursor for the nerve gas Sarin.、In the synthesis of various nerve agents、Methods of Manufacturing: Thionyl chloride is now generally produced by treating SO2 or SO3 with SCl2 at ca. 150-250 °C in the presence of activated carbon. The crude product is purified by distillation after addition of sulfur. Crude thionyl chloride production is a continuous process、but the distillation is carried out either continuously or in batches. The side product SO2 can be reacted with chlorine to give SO2Cl2 and thus recycled. ... Technical-grade thionyl chloride can contain sulfur chlorides、SO2、and SO2Cl2. Sulfur chlorides can be removed by distillation over sulfur、in some cases with the addition of FeCl3 or AlCl3. For laboratory-scale purification、distillation with triphenyl phosphite or dipentene is recommended. Modern processes give thionyl chloride in a quality which does not require any additional purification.、Prepared by the oxidation of sulfur dichloride with sulfur trioxide ... .、Edwards、United States patent 2362057 (1944 to Hooker Electrochemical) ... .、Impurities: The following impurities can be present: <、= 0.3% SO2、<、= 0.2% SO2Cl2、= 0.05% sulfur chlorides、and <、= 0.1% evaporation residue.、Formulations、Preparations: Technical-grade ... The thionyl chloride content should be min. 99.6%.、Grade: 93%、97.5%、U.S. Production: (1972) GREATER THAN 4.54X10+5 GRAMS、(1975) GREATER THAN 4.54X10+5 GRAMS、Production volumes for non-confidential chemicals reported under the Inventory Update Rule. [Table#2291]、Non-confidential 2016 Chemical Data Reporting (CDR) information on the production and use of chemicals manufactured or imported into the United States. Chemical: Thionyl chloride:、Table: National Aggregate Production Volume (pounds) [Table#2292]、General Manufacturing Information: Thionyl chloride: ACTIVE、The Chemical Weapons Convention (CWC) is an international treaty which bans the development、production、stockpiling、and transfer or use of chemical weapons. The Convention mandates the destruction and prohibition of chemical weapons and related facilities and provides for restrictions on international trade in toxic chemicals and precursors.、The Convention's monitoring and verification measures involve submission of declarations regarding ...、Schedule 1、2、and 3 chemicals、and inspections by the Organization for the Prohibition of Chemical Weapons of the facilities where these chemicals are produced. ... Schedule 3 chemicals ...、may、have been stockpiled or used as weapons、but ... are produced、and used、in large quantities for purposes not prohibited by the Convention (2). Thionyl chloride is listed in the CWC Annex on Chemicals under Schedule 3 (1).。

亚硫酰氯 属于哪个分类?

所属分类:医药中间体。

PubChem 公开数据

亚硫酰氯(CAS 7719-09-7)的独立参考数据,整理自公开化学数据库。

各数据库的登记标识

CAS Registry Number7719-09-7
PubChem CID24386
Molecular formulaCl2OS
IUPAC namethionyl dichloride
UNII (FDA)4A8YJA13N4

计算分子描述符

Molecular Weight118.97
XLogP31.5
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count2
Rotatable Bond Count0
Exact Mass117.9046912
Monoisotopic Mass117.9046912
Topological Polar Surface Area36.3
Heavy Atom Count4

在册的理化数值

Boiling Point169 °F at 760 mmHg (NIOSH, 2024)
Boiling Point76 °C at 760 mm Hg
Boiling Point76 °C
Boiling Point169 °F
Boiling Point78.8 °C @760 [mm Hg]
Melting Point-156 °F (NIOSH, 2024)
Melting Point-104.5 °C
Melting Point-156 °F
Melting Point-105 °C
Density1.676 at 0 °C/4 °C; 1.655 at 10 °C/4 °C; 1.638 at 20 °C/4 °C

在册的记载用途

    Used to make herbicides, surfactants, drugs, dyes, and plastics; Also used as an electrolyte in lithium batteries; [ACGIH]Battery Manufacturing [Category: Industry]

    同义词与商品名

    THIONYL CHLORIDE; Thionyl dichloride; 7719-09-7; Sulfinyl chloride; Sulfurous dichloride; Sulfurous oxychloride; Sulfinyl dichloride; Sulfur oxychloride; Sulfur chloride oxide; Sulfur chloride oxide (Cl2SO); 4A8YJA13N4; DTXSID3064778; CHEBI:29290; RefChem:6303; DTXCID0047953; 231-748-8

    GHS 危害分类

    Reported hazard statementsH302, H314, H332, H318 (29.4%), H331 (45.7%), H335 (38.4%), H315 (100%), H319 (100%)

    H302: Harmful if swallowed [Warning Acute toxicity, oral]

    H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

    公开数据库对它的描述

    Thionyl Chloride · CAS 7719-09-7 · Cl2OS. UNII 4A8YJA13N4. Boiling Point: 169 °F at 760 mmHg (NIOSH, 2024); Boiling Point: 76 °C at 760 mm Hg; Boiling Point: 76 °C.

    物理形态与操作说明

    数据来源:PubChem / Wikidata;与随货 COA 不一致时以 COA 为准。

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