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Naphthylamine

CAS 25168-10-9C10H9NMW 143.18

Naphthylamine (CAS 25168-10-9) — formula C10H9N, molecular weight 143.18; category organic chemicals.

Product Overview

CAS Number25168-10-9
Molecular FormulaC10H9N
Molecular Weight143.18
Melting Point122 °F (NTP, 1992)
Boiling Point574 °F at 760 mmHg (NTP, 1992)
LogP2.2
ApplicationsUses: Former uses included: a chemical intermediate for the synthesis of dyes, rubber antioxidants, and pesticides, [HSDB], See 29CFR1910.1003 (Code of Federal Regulations}, Toning prints made with cerium salts., Chemical intermediate for dyes, eg, azoic diazo component, chemical intermediate for azo dye coupling agents, for n-1-naphthylphthalmic acid herbicide, for n-phenyl-1-naphthylamine rubber antioxidant, for an imidazoline adrenergic agent, chemical intermediate for 1-naphthylthiourea rodenticide and for a fluoroacetamide miticide., SRP60: Former, 1-Naphthylamine is used as an intermediate in the synthesis of dyes, antioxidants, herbicides, some drugs, and other chemicals., In agricultural chemicals, Methods of Manufacturing: Reduction of 1-nitronaphthalene by catalytic hydrogenation with a nickel catalyst ... ., Prepared by reducing alpha-nitronaphthalene with iron and hydrochloric acid., Naphthalene is nitrated with H2SO4-HNO3 at 50-60 °C. The crude product (mp 52 °C) is separated, washed with hot water, and further purified by crystallization or sweating (draining of the lower melting point isomer) to remove 2-nitronaphthalene (3%) and traces of 2, 4-dinitronaphthalene. purified 1-nitronaphthalene was traditionally reduced with iron in boiling dilute hydrochloric acid, but modern plants use hydrogenation with nickel catalyst. The 1-naphthylamine produced is further purified by distillation under vacuum. The content of 2-naphthylamine in the commercial product is specified at less than 10 ppm., Impurities: Most commercial 1-naphthylamine ... contains 4-10% of 2-naphthylamine if synthesized by methods used in previous decades. Modern production methods give rise to a max of 0.5%., U.S. Production: (1978) PROBABLY GREATER THAN 2.27X10+6 G, (1982) PROBABLY GREATER THAN 2.27X10+6 G, (1985) Data not reported, U.S. Imports: (1977) 5.16X10+7 G (PRINCPL CUSTMS DISTS), (1982) 9.91X10+7 G (PRINCPL CUSTMS DISTS), General Manufacturing Information: 1-Naphthalenamine: ACTIVE
CategoryOrganic Chemicals

Applications

Documented applications: Uses: Former uses included: a chemical intermediate for the synthesis of dyes, rubber antioxidants, and pesticides, [HSDB], See 29CFR1910.1003 (Code of Federal Regulations}, Toning prints made with cerium salts., Chemical intermediate for dyes, eg, azoic diazo component, chemical intermediate for azo dye coupling agents, for n-1-naphthylphthalmic acid herbicide, for n-phenyl-1-naphthylamine rubber antioxidant, for an imidazoline adrenergic agent, chemical intermediate for 1-naphthylthiourea rodenticide and for a fluoroacetamide miticide., SRP60: Former, 1-Naphthylamine is used as an intermediate in the synthesis of dyes, antioxidants, herbicides, some drugs, and other chemicals., In agricultural chemicals, Methods of Manufacturing: Reduction of 1-nitronaphthalene by catalytic hydrogenation with a nickel catalyst ... ., Prepared by reducing alpha-nitronaphthalene with iron and hydrochloric acid., Naphthalene is nitrated with H2SO4-HNO3 at 50-60 °C. The crude product (mp 52 °C) is separated, washed with hot water, and further purified by crystallization or sweating (draining of the lower melting point isomer) to remove 2-nitronaphthalene (3%) and traces of 2, 4-dinitronaphthalene. purified 1-nitronaphthalene was traditionally reduced with iron in boiling dilute hydrochloric acid, but modern plants use hydrogenation with nickel catalyst. The 1-naphthylamine produced is further purified by distillation under vacuum. The content of 2-naphthylamine in the commercial product is specified at less than 10 ppm., Impurities: Most commercial 1-naphthylamine ... contains 4-10% of 2-naphthylamine if synthesized by methods used in previous decades. Modern production methods give rise to a max of 0.5%., U.S. Production: (1978) PROBABLY GREATER THAN 2.27X10+6 G, (1982) PROBABLY GREATER THAN 2.27X10+6 G, (1985) Data not reported, U.S. Imports: (1977) 5.16X10+7 G (PRINCPL CUSTMS DISTS), (1982) 9.91X10+7 G (PRINCPL CUSTMS DISTS), General Manufacturing Information: 1-Naphthalenamine: ACTIVE.

Technical Profile

What this product is

Naphthylamine is a carbon-based organic compound with CAS registry number 25168-10-9 and molecular formula C10H9N (molecular weight 143.18), belonging to the organic chemicals segment of chemical raw materials.

Identification

CAS number: 25168-10-9

Its molecular formula C10H9N comprises 10 C, 9 H, 1 N atoms.

Also known as: Naphthylamine · 萘胺

Category: organic chemicals

Frequently Asked Questions

What is the CAS number of Naphthylamine?

The CAS registry number of Naphthylamine is 25168-10-9.

What is the molecular formula and molecular weight of Naphthylamine?

Molecular formula C10H9N, molecular weight 143.18.

What other names is Naphthylamine known by?

It is also registered under: Naphthylamine, 萘胺.

What are the documented applications of Naphthylamine?

Recorded applications: Uses: Former uses included: a chemical intermediate for the synthesis of dyes, rubber antioxidants, and pesticides, [HSDB], See 29CFR1910.1003 (Code of Federal Regulations}, Toning prints made with cerium salts., Chemical intermediate for dyes, eg, azoic diazo component, chemical intermediate for azo dye coupling agents, for n-1-naphthylphthalmic acid herbicide, for n-phenyl-1-naphthylamine rubber antioxidant, for an imidazoline adrenergic agent, chemical intermediate for 1-naphthylthiourea rodenticide and for a fluoroacetamide miticide., SRP60: Former, 1-Naphthylamine is used as an intermediate in the synthesis of dyes, antioxidants, herbicides, some drugs, and other chemicals., In agricultural chemicals, Methods of Manufacturing: Reduction of 1-nitronaphthalene by catalytic hydrogenation with a nickel catalyst ... ., Prepared by reducing alpha-nitronaphthalene with iron and hydrochloric acid., Naphthalene is nitrated with H2SO4-HNO3 at 50-60 °C. The crude product (mp 52 °C) is separated, washed with hot water, and further purified by crystallization or sweating (draining of the lower melting point isomer) to remove 2-nitronaphthalene (3%) and traces of 2, 4-dinitronaphthalene. purified 1-nitronaphthalene was traditionally reduced with iron in boiling dilute hydrochloric acid, but modern plants use hydrogenation with nickel catalyst. The 1-naphthylamine produced is further purified by distillation under vacuum. The content of 2-naphthylamine in the commercial product is specified at less than 10 ppm., Impurities: Most commercial 1-naphthylamine ... contains 4-10% of 2-naphthylamine if synthesized by methods used in previous decades. Modern production methods give rise to a max of 0.5%., U.S. Production: (1978) PROBABLY GREATER THAN 2.27X10+6 G, (1982) PROBABLY GREATER THAN 2.27X10+6 G, (1985) Data not reported, U.S. Imports: (1977) 5.16X10+7 G (PRINCPL CUSTMS DISTS), (1982) 9.91X10+7 G (PRINCPL CUSTMS DISTS), General Manufacturing Information: 1-Naphthalenamine: ACTIVE.

Which category does Naphthylamine belong to?

Category: Organic Chemicals.

PubChem Public Data

Independent reference data for Naphthylamine (CAS 25168-10-9), compiled from public chemistry databases.

Registry identifiers across databases

CAS Registry Number25168-10-9
PubChem CID8640
Molecular formulaC10H9N
IUPAC namenaphthalen-1-amine
UNII (FDA)9753I242R5

Computed descriptors

Molecular Weight143.18
XLogP32.2
Hydrogen Bond Donor Count1
Hydrogen Bond Acceptor Count1
Rotatable Bond Count0
Exact Mass143.073499291
Monoisotopic Mass143.073499291
Topological Polar Surface Area26
Heavy Atom Count11

Physicochemical values on record

Boiling Point574 °F at 760 mmHg (NTP, 1992)
Boiling Point300.7 °C
Boiling Point300.8 °C
Boiling Point573 °F
Boiling Point300.7 °C @760 [mm Hg]
Melting Point122 °F (NTP, 1992)
Melting Point49.2 °C
Melting Point50.0 °C
Melting Point122 °F
Flash Point315 °F (NTP, 1992)

Documented uses on record

    See 29CFR1910.1003 (Code of Federal Regulations}Toning prints made with cerium salts.

    Synonyms and trade names

    1-NAPHTHYLAMINE; 1-Aminonaphthalene; 134-32-7; naphthalen-1-amine; 1-Naphthalenamine; alpha-Naphthylamine; Naphthalidine; Naphthalen-1-ylamine; Fast Garnet Base B; Naphthalidam; 1-Naphthalamine; 1-Naphthylamin; 1-Naftilamina; alpha-Aminonaphthalene; Alfanaftilamina; Fast Garnet B Base

    Regulatory listings held on file

    Regulatory & Food ContactFDA Inventory of Food Contact Substances Listed in 21 CFR: FCS

    GHS hazard classification

    Reported hazard statementsH302, H411, H310 (13.6%), H311 (37.5%), H317 (37.5%), H320, H371

    H302: Harmful if swallowed [Warning Acute toxicity, oral]

    H411: Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

    What the public record says

    Naphthylamine · CAS 25168-10-9 · C10H9N. UNII 9753I242R5. Boiling Point: 574 °F at 760 mmHg (NTP, 1992); Boiling Point: 300.7 °C; Boiling Point: 300.8 °C.

    Physical description and handling notes

    Source: PubChem / Wikidata; the batch COA governs where values differ.

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