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Lead(IV) acetate

CAS 546-67-8C8H12O8Pb-2MW 443

Lead(IV) acetate (CAS 546-67-8) — formula C8H12O8Pb-2, molecular weight 443; category organic chemicals.

Product Overview

CAS Number546-67-8
Molecular FormulaC8H12O8Pb-2
Molecular Weight443
Melting Point347 °F (USCG, 1999)
ApplicationsUses: Used in organic syntheses, [HSDB], Often used as an oxidizing agent in organic syntheses because it is highly selective in cleaving vicinal glycols. It also readily cleaves alpha-hydroxy acids, such as oxalic acid, at room temperature. Another use is for the introduction of acetoxy groups in organic molecules., Methods of Manufacturing: Prepd from Pb3O4 and glacial acetic acid preferably in the presence of some acetic anhydride, ... Prepn by electrolysis.[The Merck Index, Fourteenth Edition (2006), ... Prepared by adding warm, anhydrous, glacial acetic acid to red lead (Pb3O4) and subsequently cooling the solution., Formulations, Preparations: Grades: Commercial, 80-90%., Colorless to faintly pink crystals stored in glacial acetic acid., General Manufacturing Information: Acetic acid, lead(4+) salt (4:1): ACTIVE
CategoryOrganic Chemicals

Applications

Documented applications: Uses: Used in organic syntheses, [HSDB], Often used as an oxidizing agent in organic syntheses because it is highly selective in cleaving vicinal glycols. It also readily cleaves alpha-hydroxy acids, such as oxalic acid, at room temperature. Another use is for the introduction of acetoxy groups in organic molecules., Methods of Manufacturing: Prepd from Pb3O4 and glacial acetic acid preferably in the presence of some acetic anhydride, ... Prepn by electrolysis.[The Merck Index, Fourteenth Edition (2006), ... Prepared by adding warm, anhydrous, glacial acetic acid to red lead (Pb3O4) and subsequently cooling the solution., Formulations, Preparations: Grades: Commercial, 80-90%., Colorless to faintly pink crystals stored in glacial acetic acid., General Manufacturing Information: Acetic acid, lead(4+) salt (4:1): ACTIVE.

Technical Profile

What this product is

Lead(IV) acetate is a carbon-based organic compound with CAS registry number 546-67-8 and molecular formula C8H12O8Pb-2 (molecular weight 443), belonging to the organic chemicals segment of chemical raw materials.

Identification

CAS number: 546-67-8

Its molecular formula C8H12O8Pb-2 comprises 8 C, 12 H, 8 O, 1 Pb atoms.

Also known as: Lead(IV) acetate · 醋酸铅(IV)

Category: organic chemicals

Frequently Asked Questions

What is the CAS number of Lead(IV) acetate?

The CAS registry number of Lead(IV) acetate is 546-67-8.

What is the molecular formula and molecular weight of Lead(IV) acetate?

Molecular formula C8H12O8Pb-2, molecular weight 443.

What other names is Lead(IV) acetate known by?

It is also registered under: Lead(IV) acetate, 醋酸铅(IV).

What are the documented applications of Lead(IV) acetate?

Recorded applications: Uses: Used in organic syntheses, [HSDB], Often used as an oxidizing agent in organic syntheses because it is highly selective in cleaving vicinal glycols. It also readily cleaves alpha-hydroxy acids, such as oxalic acid, at room temperature. Another use is for the introduction of acetoxy groups in organic molecules., Methods of Manufacturing: Prepd from Pb3O4 and glacial acetic acid preferably in the presence of some acetic anhydride, ... Prepn by electrolysis.[The Merck Index, Fourteenth Edition (2006), ... Prepared by adding warm, anhydrous, glacial acetic acid to red lead (Pb3O4) and subsequently cooling the solution., Formulations, Preparations: Grades: Commercial, 80-90%., Colorless to faintly pink crystals stored in glacial acetic acid., General Manufacturing Information: Acetic acid, lead(4+) salt (4:1): ACTIVE.

Which category does Lead(IV) acetate belong to?

Category: Organic Chemicals.

PubChem Public Data

Independent reference data for Lead(IV) acetate (CAS 546-67-8), compiled from public chemistry databases.

Registry identifiers across databases

CAS Registry Number546-67-8
PubChem CID11025
Molecular formulaC8H12O8Pb-2
IUPAC namelead(2+) tetraacetate
UNII (FDA)CFN24B03DB

Computed descriptors

Molecular Weight443
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count8
Rotatable Bond Count0
Exact Mass444.02987
Monoisotopic Mass444.02987
Topological Polar Surface Area161
Heavy Atom Count17

Physicochemical values on record

Melting Point347 °F (USCG, 1999)
Melting Point175-180 °C
Density2.228 at 17 °C/4 °C
Formulations/PreparationsGrades: Commercial, 80-90%.

Documented uses on record

    Used in organic syntheses; [HSDB]Often used as an oxidizing agent in organic syntheses because it is highly selective in cleaving vicinal glycols. It also readily cleaves alpha-hydroxy acids, such as oxalic acid, at room temperature. Another use is for the introduction of acetoxy groups in organic molecules.

    Synonyms and trade names

    LEAD TETRAACETATE; 546-67-8; Plumbic acetate; Lead(IV) acetate; Lead tetracetate; Lead acetate, tetra-; Lead acetate (Pb(OAc)4); Acetic acid, lead(4+) salt; Lead acetate (Pb(O2C2H3)4); CFN24B03DB; Lead (IV) Acetate; lead(4+) tetraacetate; DTXSID6041058; RefChem:152659; lambda2-lead(2+) ion tetraacetate; 208-908-0

    GHS hazard classification

    Reported hazard statementsH302, H332 (59.3%), H360 (40.7%), H373 (98.9%), H400 (98.9%), H410 (99.4%), H341, H351

    H302+H332 (59.3%): Harmful if swallowed or if inhaled [Warning Acute toxicity, oral; acute toxicity, inhalation]

    H302 (97.7%): Harmful if swallowed [Warning Acute toxicity, oral]

    What the public record says

    Lead(IV) acetate · CAS 546-67-8 · C8H12O8Pb-2. UNII CFN24B03DB. Melting Point: 347 °F (USCG, 1999); Melting Point: 175-180 °C; Density: 2.228 at 17 °C/4 °C.

    Physical description and handling notes

    Source: PubChem / Wikidata; the batch COA governs where values differ.

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