Iron(III) dimethyldithiocarbamate (CAS 14484-64-1) — formula C9H18FeN3S6, molecular weight 416.5; category organic chemicals.
| CAS Number | 14484-64-1 |
|---|---|
| Molecular Formula | C9H18FeN3S6 |
| Molecular Weight | 416.5 |
| Melting Point | 180 °C |
| LogP | log Kow = -1.60 |
| Applications | Uses: Fungicide used on fruit, nuts, vegetables, ornamental crops, in household applications, [HSDB], Farming (Pesticides) [Category: Industry], For ferbam (USEPA, OPP Pesticide Code: 034801) ACTIVE products with label matches., SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses., Fungicide used on fruit, in household applications., It is mainly used for protection of foliage against fungal pathogens including taphrina deformans of peaches at 175 g, 100 L., For citrus to control postbloom fruit drop., Methods of Manufacturing: Dimethyl amine and carbon disulfide react to give dimethylthiocarbamate. Reaction of that material with soluble ferric salts gives ferbam., Prepared from sodium dimethyldithiocarbamate and a solution of a ferric salt, Formulations, Preparations: Grades: 76% wettable powder, 87% technical powder., Mixtures include: 'Trimanzone', wettable powder, ferbam + manganese ethylenebis(dithiocarbamate) + zinc ethylenebis(dithiocarbamate)., Water dispersible granules, Often used in combinations with dithiocarbamates to extend the spectrum of activity., For more Formulations, Preparations (Complete) data for FERBAM (18 total), please visit the HSDB record page., Consumption Patterns: 3.5X10+5 lbs a.i., yr used in US agriculture (1989), In US, used on apples, cherries, cranberries, grapes, peaches, pears, raspberries, and tobacco (1987 Census of Agriculture), 30% is used on peaches, apricots, plums, prunes, and nectarines, 25% is used on citrus fruit, 23% on other fruits and nuts, 15% on apples, 7% on field crops including vegetables and peanuts (1971)., U.S. Production: (1972) 8.63X10+8 G, (1975) 3.2X10+8 G (CONSUMPTION), General Manufacturing Information: Iron, tris(N, N-dimethylcarbamodithioato-.kappa.S, .kappa.S')-, (OC-6-11)-: ACTIVE, It is incompatible with copper or mercury compounds or alkaline pesticides., ... Used as fungicide to control diseases of plants, particularly those affecting apples & tobacco ... and is registered for use on about 75 agricultural and ornamental plants ... . Used on agricultural crops in USA ... ., Ferbam has a complex pattern of stimulatory and fungitoxic zones similar to other measured dimethyldithiocarbamate fungicides indicating that their degradation products (presumably in the original product or due to dissociation of the metal atom) may be identical as well as fungitoxic. |
| Category | Organic Chemicals |
Documented applications: Uses: Fungicide used on fruit, nuts, vegetables, ornamental crops, in household applications, [HSDB], Farming (Pesticides) [Category: Industry], For ferbam (USEPA, OPP Pesticide Code: 034801) ACTIVE products with label matches., SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses., Fungicide used on fruit, in household applications., It is mainly used for protection of foliage against fungal pathogens including taphrina deformans of peaches at 175 g, 100 L., For citrus to control postbloom fruit drop., Methods of Manufacturing: Dimethyl amine and carbon disulfide react to give dimethylthiocarbamate. Reaction of that material with soluble ferric salts gives ferbam., Prepared from sodium dimethyldithiocarbamate and a solution of a ferric salt, Formulations, Preparations: Grades: 76% wettable powder, 87% technical powder., Mixtures include: 'Trimanzone', wettable powder, ferbam + manganese ethylenebis(dithiocarbamate) + zinc ethylenebis(dithiocarbamate)., Water dispersible granules, Often used in combinations with dithiocarbamates to extend the spectrum of activity., For more Formulations, Preparations (Complete) data for FERBAM (18 total), please visit the HSDB record page., Consumption Patterns: 3.5X10+5 lbs a.i., yr used in US agriculture (1989), In US, used on apples, cherries, cranberries, grapes, peaches, pears, raspberries, and tobacco (1987 Census of Agriculture), 30% is used on peaches, apricots, plums, prunes, and nectarines, 25% is used on citrus fruit, 23% on other fruits and nuts, 15% on apples, 7% on field crops including vegetables and peanuts (1971)., U.S. Production: (1972) 8.63X10+8 G, (1975) 3.2X10+8 G (CONSUMPTION), General Manufacturing Information: Iron, tris(N, N-dimethylcarbamodithioato-.kappa.S, .kappa.S')-, (OC-6-11)-: ACTIVE, It is incompatible with copper or mercury compounds or alkaline pesticides., ... Used as fungicide to control diseases of plants, particularly those affecting apples & tobacco ... and is registered for use on about 75 agricultural and ornamental plants ... . Used on agricultural crops in USA ... ., Ferbam has a complex pattern of stimulatory and fungitoxic zones similar to other measured dimethyldithiocarbamate fungicides indicating that their degradation products (presumably in the original product or due to dissociation of the metal atom) may be identical as well as fungitoxic..
Iron(III) dimethyldithiocarbamate is a carbon-based organic compound with CAS registry number 14484-64-1 and molecular formula C9H18FeN3S6 (molecular weight 416.5), belonging to the organic chemicals segment of chemical raw materials.
CAS number: 14484-64-1
Its molecular formula C9H18FeN3S6 comprises 9 C, 18 H, 1 Fe, 3 N, 6 S atoms.
Also known as: Iron(III) dimethyldithiocarbamate · Ferbam
Category: organic chemicals
The CAS registry number of Iron(III) dimethyldithiocarbamate is 14484-64-1.
Molecular formula C9H18FeN3S6, molecular weight 416.5.
It is also registered under: Iron(III) dimethyldithiocarbamate, Ferbam.
Recorded applications: Uses: Fungicide used on fruit, nuts, vegetables, ornamental crops, in household applications, [HSDB], Farming (Pesticides) [Category: Industry], For ferbam (USEPA, OPP Pesticide Code: 034801) ACTIVE products with label matches., SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses., Fungicide used on fruit, in household applications., It is mainly used for protection of foliage against fungal pathogens including taphrina deformans of peaches at 175 g, 100 L., For citrus to control postbloom fruit drop., Methods of Manufacturing: Dimethyl amine and carbon disulfide react to give dimethylthiocarbamate. Reaction of that material with soluble ferric salts gives ferbam., Prepared from sodium dimethyldithiocarbamate and a solution of a ferric salt, Formulations, Preparations: Grades: 76% wettable powder, 87% technical powder., Mixtures include: 'Trimanzone', wettable powder, ferbam + manganese ethylenebis(dithiocarbamate) + zinc ethylenebis(dithiocarbamate)., Water dispersible granules, Often used in combinations with dithiocarbamates to extend the spectrum of activity., For more Formulations, Preparations (Complete) data for FERBAM (18 total), please visit the HSDB record page., Consumption Patterns: 3.5X10+5 lbs a.i., yr used in US agriculture (1989), In US, used on apples, cherries, cranberries, grapes, peaches, pears, raspberries, and tobacco (1987 Census of Agriculture), 30% is used on peaches, apricots, plums, prunes, and nectarines, 25% is used on citrus fruit, 23% on other fruits and nuts, 15% on apples, 7% on field crops including vegetables and peanuts (1971)., U.S. Production: (1972) 8.63X10+8 G, (1975) 3.2X10+8 G (CONSUMPTION), General Manufacturing Information: Iron, tris(N, N-dimethylcarbamodithioato-.kappa.S, .kappa.S')-, (OC-6-11)-: ACTIVE, It is incompatible with copper or mercury compounds or alkaline pesticides., ... Used as fungicide to control diseases of plants, particularly those affecting apples & tobacco ... and is registered for use on about 75 agricultural and ornamental plants ... . Used on agricultural crops in USA ... ., Ferbam has a complex pattern of stimulatory and fungitoxic zones similar to other measured dimethyldithiocarbamate fungicides indicating that their degradation products (presumably in the original product or due to dissociation of the metal atom) may be identical as well as fungitoxic..
Category: Organic Chemicals.
Independent reference data for Iron(III) dimethyldithiocarbamate (CAS 14484-64-1), compiled from public chemistry databases.
| CAS Registry Number | 14484-64-1 |
|---|---|
| PubChem CID | 26710 |
| Molecular formula | C9H18FeN3S6 |
| IUPAC name | tris(N,N-dimethylcarbamodithioate);iron(3+) |
| UNII (FDA) | SKM8W5154H |
| Molecular Weight | 416.5 |
|---|---|
| Hydrogen Bond Donor Count | 0 |
| Hydrogen Bond Acceptor Count | 6 |
| Rotatable Bond Count | 0 |
| Exact Mass | 415.917435 |
| Monoisotopic Mass | 415.917435 |
| Topological Polar Surface Area | 109 |
| Heavy Atom Count | 19 |
| Melting Point | 180 °C |
|---|---|
| Solubility | 0.01 % (NIOSH, 2024) |
| Solubility | In water, 130 mg/L at 25 °C |
| Solubility | 0.01% |
| Density | approx 0.6 kg/L |
| Vapor Pressure | 0 mmHg (approx) (NIOSH, 2024) |
| Vapor Pressure | 0 mmHg (approx) |
| LogP | log Kow = -1.60 |
| Decomposition | ...Decomposes above 180 °C |
| Decomposition | 180 °C |
Ferbam; 14484-64-1; Ferric dimethyldithiocarbamate; Iron(III) dimethyldithiocarbamate; Trimanzone; Cormate; DTXSID8020624; Fermacide; Fermate; Ferradow; Hexaferb; Hokmate; Karbam Black; Iron, tris(dimethyldithiocarbamato)-; Iron dimethyldithiocarbamate; DTXCID20624
| Reported hazard statements | H315, H319, H335, H400, H410, H320, H330, H336 |
|---|
H315: Causes skin irritation [Warning Skin corrosion/irritation]
H319: Causes serious eye irritation [Warning Serious eye damage/eye irritation]
Iron(III) dimethyldithiocarbamate · CAS 14484-64-1 · C9H18FeN3S6. UNII SKM8W5154H. Melting Point: 180 °C; Solubility: 0.01 % (NIOSH, 2024); Solubility: In water, 130 mg/L at 25 °C.
Source: PubChem / Wikidata; the batch COA governs where values differ.
Supplier: Jinan Shenghe Chemical Co., Ltd.