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Cacodylic Acid

CAS 917-76-0C2H7AsO2MW 138.00

Cacodylic Acid (CAS 917-76-0) — formula C2H7AsO2, molecular weight 138.00; category organic chemicals.

Product Overview

CAS Number917-76-0
Molecular FormulaC2H7AsO2
Molecular Weight138.00
Melting Point383 to 385 °F (NTP, 1992)
Boiling Point>200 °C
ApplicationsUses: Used as a herbicide, [Sullivan, p. 981] Used as a drug (dermatological and veterinarian), [Merck Index] Used as a preharvest desiccant, a soil sterilant, a chemical warfare agent, a timber thinning defoliant, and a sugarcane ripener, [HSDB] Used as a defoliant and herbicide registered to control weeds under non-bearing citrus trees, around buildings, and for lawn renovation, [Reference #1], Farming (Pesticides) [Category: Industry], For Dimethylarsenic Acid (USEPA, OPP Pesticide Code: 012501) ACTIVE products with label matches., SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses., PREHARVEST DESSICANT, Herbicide, soil sterilant, chemical warfare, timber thinning., Cacodylic acid is a contact herbicide which defoliates or desiccates a large variety of plants., For more Uses (Complete) data for DIMETHYLARSENIC ACID (10 total), please visit the HSDB record page., Dimethylarsinic acid is used as an herbicide and pesticide. (L180), Sodium dimethylarsinate is used as a drug in veterinary medicine to treat anaemia and eczema, and is also an herbicide., Household Products: Information on 2 consumer products that contain Dimethylarsinic acid in the following categories is provided:, • Landscaping, Yard, • Pesticides, Methods of Manufacturing: ALKYLATION OF DISODIUM METHANEARSONATE WITH METHYL CHLORIDE FOLLOWED BY ADDITION OF HYDROCHLORIC ACID., MOST CACODYLIC ACID IS MADE COMMERCIALLY BY REACTING THE MONOSODIUM SALT OF METHANEARSONIC ACID WITH METHYL CHLORIDE @ 5 PSI & 80 °C ... ., By distilling a mixture of arsenic trioxide and potassium acetate, and oxidizing the resulting product with mercuric oxide., ... Prepared commercially by the alkylation of methanearsonic acid, disodium salt with methyl chloride, followed by addition of hydrochloric acid ... ., Impurities: Dimethylarsinic acid is available as a technical grade, containing 65% active ingredient and the following possible impurities: sodium chloride, sodium sulfate, methylarsonic acid and arsenic acid., Formulations, Preparations: USEPA, OPP Pesticide Code 012501, Trade Names: Silvisar 510, Arsan, Phytar 560, component of (with 012502), Rad-E-Cate 35., PHYTAR 560 (2.48 LB, GAL CACODYLIC ACID EQUIVALENT AS SODIUM SALT), PHYTAR 138 (65% CADODYLIC ACID), PHYTAR 160 (3.25 LB, GAL CACODYLIC ACID EQUIV)., Fisher purified cacodylic acid contains 95.5% cacodylic acid., Concentrated solution, For more Formulations, Preparations (Complete) data for DIMETHYLARSENIC ACID (9 total), Consumption Patterns: COTTON USES, 25%, INDUSTRIAL, COMMERCIAL USES-EG, WEED CONTROL ON UTILITY & RAILROAD COMPANY RIGHTS-OF-WAY, 75% (1978), U.S. Production: (1978) 1.27X10+9 G, (1981) PROBABLY GREATER THAN 2.27X10+6 G, General Manufacturing Information: Arsinic acid, As, As-dimethyl-: ACTIVE, CACODYLIC ACID WAS KNOWN PRIOR TO 1900 & WAS USED MEDICALLY. ... CACODYLIC ACID PROVED TO BE A BETTER SOIL STERILIZER THAN METHANEARSONIC ACID, SODIUM ARSENITE, & SEVERAL OTHER ... &, WITH, DALAPON SPRAYS CONTROLLED ORCHARDGRASS & KENTUCKY BLUEGRASS., Used as a directed spray, postemergence. Rates: 3 to 10 lb, acre. Mix with water plus 2 qt surfactant per 100 gal of solution and apply at 40 gallons per acre. All formulations are 100% water soluble.
CategoryOrganic Chemicals

Applications

Documented applications: Uses: Used as a herbicide, [Sullivan, p. 981] Used as a drug (dermatological and veterinarian), [Merck Index] Used as a preharvest desiccant, a soil sterilant, a chemical warfare agent, a timber thinning defoliant, and a sugarcane ripener, [HSDB] Used as a defoliant and herbicide registered to control weeds under non-bearing citrus trees, around buildings, and for lawn renovation, [Reference #1], Farming (Pesticides) [Category: Industry], For Dimethylarsenic Acid (USEPA, OPP Pesticide Code: 012501) ACTIVE products with label matches., SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses., PREHARVEST DESSICANT, Herbicide, soil sterilant, chemical warfare, timber thinning., Cacodylic acid is a contact herbicide which defoliates or desiccates a large variety of plants., For more Uses (Complete) data for DIMETHYLARSENIC ACID (10 total), please visit the HSDB record page., Dimethylarsinic acid is used as an herbicide and pesticide. (L180), Sodium dimethylarsinate is used as a drug in veterinary medicine to treat anaemia and eczema, and is also an herbicide., Household Products: Information on 2 consumer products that contain Dimethylarsinic acid in the following categories is provided:, • Landscaping, Yard, • Pesticides, Methods of Manufacturing: ALKYLATION OF DISODIUM METHANEARSONATE WITH METHYL CHLORIDE FOLLOWED BY ADDITION OF HYDROCHLORIC ACID., MOST CACODYLIC ACID IS MADE COMMERCIALLY BY REACTING THE MONOSODIUM SALT OF METHANEARSONIC ACID WITH METHYL CHLORIDE @ 5 PSI & 80 °C ... ., By distilling a mixture of arsenic trioxide and potassium acetate, and oxidizing the resulting product with mercuric oxide., ... Prepared commercially by the alkylation of methanearsonic acid, disodium salt with methyl chloride, followed by addition of hydrochloric acid ... ., Impurities: Dimethylarsinic acid is available as a technical grade, containing 65% active ingredient and the following possible impurities: sodium chloride, sodium sulfate, methylarsonic acid and arsenic acid., Formulations, Preparations: USEPA, OPP Pesticide Code 012501, Trade Names: Silvisar 510, Arsan, Phytar 560, component of (with 012502), Rad-E-Cate 35., PHYTAR 560 (2.48 LB, GAL CACODYLIC ACID EQUIVALENT AS SODIUM SALT), PHYTAR 138 (65% CADODYLIC ACID), PHYTAR 160 (3.25 LB, GAL CACODYLIC ACID EQUIV)., Fisher purified cacodylic acid contains 95.5% cacodylic acid., Concentrated solution, For more Formulations, Preparations (Complete) data for DIMETHYLARSENIC ACID (9 total), Consumption Patterns: COTTON USES, 25%, INDUSTRIAL, COMMERCIAL USES-EG, WEED CONTROL ON UTILITY & RAILROAD COMPANY RIGHTS-OF-WAY, 75% (1978), U.S. Production: (1978) 1.27X10+9 G, (1981) PROBABLY GREATER THAN 2.27X10+6 G, General Manufacturing Information: Arsinic acid, As, As-dimethyl-: ACTIVE, CACODYLIC ACID WAS KNOWN PRIOR TO 1900 & WAS USED MEDICALLY. ... CACODYLIC ACID PROVED TO BE A BETTER SOIL STERILIZER THAN METHANEARSONIC ACID, SODIUM ARSENITE, & SEVERAL OTHER ... &, WITH, DALAPON SPRAYS CONTROLLED ORCHARDGRASS & KENTUCKY BLUEGRASS., Used as a directed spray, postemergence. Rates: 3 to 10 lb, acre. Mix with water plus 2 qt surfactant per 100 gal of solution and apply at 40 gallons per acre. All formulations are 100% water soluble..

Technical Profile

What this product is

Cacodylic Acid is a carbon-based organic compound with CAS registry number 917-76-0 and molecular formula C2H7AsO2 (molecular weight 138.00), belonging to the organic chemicals segment of chemical raw materials.

Identification

CAS number: 917-76-0

Its molecular formula C2H7AsO2 comprises 2 C, 7 H, 1 As, 2 O atoms.

Also known as: Cacodylic Acid · 二甲胂酸

Category: organic chemicals

Frequently Asked Questions

What is the CAS number of Cacodylic Acid?

The CAS registry number of Cacodylic Acid is 917-76-0.

What is the molecular formula and molecular weight of Cacodylic Acid?

Molecular formula C2H7AsO2, molecular weight 138.00.

What other names is Cacodylic Acid known by?

It is also registered under: Cacodylic Acid, 二甲胂酸.

What are the documented applications of Cacodylic Acid?

Recorded applications: Uses: Used as a herbicide, [Sullivan, p. 981] Used as a drug (dermatological and veterinarian), [Merck Index] Used as a preharvest desiccant, a soil sterilant, a chemical warfare agent, a timber thinning defoliant, and a sugarcane ripener, [HSDB] Used as a defoliant and herbicide registered to control weeds under non-bearing citrus trees, around buildings, and for lawn renovation, [Reference #1], Farming (Pesticides) [Category: Industry], For Dimethylarsenic Acid (USEPA, OPP Pesticide Code: 012501) ACTIVE products with label matches., SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses., PREHARVEST DESSICANT, Herbicide, soil sterilant, chemical warfare, timber thinning., Cacodylic acid is a contact herbicide which defoliates or desiccates a large variety of plants., For more Uses (Complete) data for DIMETHYLARSENIC ACID (10 total), please visit the HSDB record page., Dimethylarsinic acid is used as an herbicide and pesticide. (L180), Sodium dimethylarsinate is used as a drug in veterinary medicine to treat anaemia and eczema, and is also an herbicide., Household Products: Information on 2 consumer products that contain Dimethylarsinic acid in the following categories is provided:, • Landscaping, Yard, • Pesticides, Methods of Manufacturing: ALKYLATION OF DISODIUM METHANEARSONATE WITH METHYL CHLORIDE FOLLOWED BY ADDITION OF HYDROCHLORIC ACID., MOST CACODYLIC ACID IS MADE COMMERCIALLY BY REACTING THE MONOSODIUM SALT OF METHANEARSONIC ACID WITH METHYL CHLORIDE @ 5 PSI & 80 °C ... ., By distilling a mixture of arsenic trioxide and potassium acetate, and oxidizing the resulting product with mercuric oxide., ... Prepared commercially by the alkylation of methanearsonic acid, disodium salt with methyl chloride, followed by addition of hydrochloric acid ... ., Impurities: Dimethylarsinic acid is available as a technical grade, containing 65% active ingredient and the following possible impurities: sodium chloride, sodium sulfate, methylarsonic acid and arsenic acid., Formulations, Preparations: USEPA, OPP Pesticide Code 012501, Trade Names: Silvisar 510, Arsan, Phytar 560, component of (with 012502), Rad-E-Cate 35., PHYTAR 560 (2.48 LB, GAL CACODYLIC ACID EQUIVALENT AS SODIUM SALT), PHYTAR 138 (65% CADODYLIC ACID), PHYTAR 160 (3.25 LB, GAL CACODYLIC ACID EQUIV)., Fisher purified cacodylic acid contains 95.5% cacodylic acid., Concentrated solution, For more Formulations, Preparations (Complete) data for DIMETHYLARSENIC ACID (9 total), Consumption Patterns: COTTON USES, 25%, INDUSTRIAL, COMMERCIAL USES-EG, WEED CONTROL ON UTILITY & RAILROAD COMPANY RIGHTS-OF-WAY, 75% (1978), U.S. Production: (1978) 1.27X10+9 G, (1981) PROBABLY GREATER THAN 2.27X10+6 G, General Manufacturing Information: Arsinic acid, As, As-dimethyl-: ACTIVE, CACODYLIC ACID WAS KNOWN PRIOR TO 1900 & WAS USED MEDICALLY. ... CACODYLIC ACID PROVED TO BE A BETTER SOIL STERILIZER THAN METHANEARSONIC ACID, SODIUM ARSENITE, & SEVERAL OTHER ... &, WITH, DALAPON SPRAYS CONTROLLED ORCHARDGRASS & KENTUCKY BLUEGRASS., Used as a directed spray, postemergence. Rates: 3 to 10 lb, acre. Mix with water plus 2 qt surfactant per 100 gal of solution and apply at 40 gallons per acre. All formulations are 100% water soluble..

Which category does Cacodylic Acid belong to?

Category: Organic Chemicals.

PubChem Public Data

Independent reference data for Cacodylic Acid (CAS 917-76-0), compiled from public chemistry databases.

Registry identifiers across databases

CAS Registry Number917-76-0
PubChem CID2513
Molecular formulaC2H7AsO2
IUPAC namedimethylarsinic acid
UNII (FDA)AJ2HL7EU8K

Computed descriptors

Molecular Weight138.00
Hydrogen Bond Donor Count1
Hydrogen Bond Acceptor Count2
Rotatable Bond Count0
Exact Mass137.966199
Monoisotopic Mass137.966199
Topological Polar Surface Area37.3
Heavy Atom Count5

Physicochemical values on record

Boiling Point>200 °C
Melting Point383 to 385 °F (NTP, 1992)
Melting Point195 °C
SolubilityIn water, 2X10+6 mg/l @ 25 °C.
Vapor Pressure0.0000001 [mmHg]
Dissociation ConstantspKa = 1.57

Documented uses on record

    Used as a herbicide; [Sullivan, p. 981] Used as a drug (dermatological and veterinarian); [Merck Index] Used as a preharvest desiccant, a soil sterilant, a chemical warfare agent, a timber thinning defoliant, and a sugarcane ripener; [HSDB] Used as a defoliant and herbicide registered to control weeds under non-bearing citrus trees, around buildings, and for lawn renovation; [Reference #1]Herbicide; soil sterilant; chemical warfare; timber thinning.

    Synonyms and trade names

    cacodylic acid; Dimethylarsinic acid; 75-60-5; Silvisar; Phytar; Arsan; DIMETHYLARSENIC ACID; Erase; Ansar 138; Silvisar 510; Arsinic acid, dimethyl-; Phytar 560; Moncide; Sylvicor; Dilic; Agent Blue

    GHS hazard classification

    Reported hazard statementsH301 (94.2%), H331 (94.2%), H400 (90.4%), H410 (98.1%)

    H301 (94.2%): Toxic if swallowed [Danger Acute toxicity, oral]

    H331 (94.2%): Toxic if inhaled [Danger Acute toxicity, inhalation]

    What the public record says

    Cacodylic Acid · CAS 917-76-0 · C2H7AsO2. UNII AJ2HL7EU8K. Boiling Point: >200 °C; Melting Point: 383 to 385 °F (NTP, 1992); Melting Point: 195 °C.

    Physical description and handling notes

    Source: PubChem / Wikidata; the batch COA governs where values differ.

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