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AROCLOR 1016, 1X5ML, TRANSFORMER OIL 50M G/KG

CAS 12674-11-2C12H7Cl3MW 257.5

AROCLOR 1016, 1X5ML, TRANSFORMER OIL 50M G/KG (CAS 12674-11-2) — formula C12H7Cl3, molecular weight 257.5; category organic chemicals.

Product Overview

CAS Number12674-11-2
Molecular FormulaC12H7Cl3
Molecular Weight257.5
Boiling Point725 to 788 °F at 760 mmHg (NTP, 1992)
LogPlog Kow = 4.38
ApplicationsUses: Although the production and sale was discontinued in late 1977, it is still present in ... capacitors now in use., Chlorinated biphenyls and related compounds, Summary of former end uses for various Aroclors:, Table: Aroclor [Table#5901], PCBs were used as coolants and lubricants in transformers, capacitors, and other electrical devices (such as fluorescent lights and refridgerators) produced before 1977. PCBs may contaminate the air and water near hazardous waste sites. In addition, PCBs bioaccumulate in the environment and may be found in fish, meat, and dairy products. (L4), Methods of Manufacturing: PCBs, were, ... prepared industrially by the chlorination of biphenyl with anhydrous chlorine in the presence of a catalyst such as iron filings or ferric chloride. The products are complex mixtures of chlorobiphenyls, whose degree of chlorination depends principally on the time of contact (12-36 hr) of the biphenyl with anhydrous chlorine. The crude product is blown with air, and a small amount of lime is added to remove hydrogen chloride and ferric chloride. The resulting chlorinated mixtures are batch-distilled to remove color and traces of hydrogen chloride and ferric chloride., Polychlorinated biphenyls, Impurities: Almost without exception, polychlorinated biphenyls contain various levels of polychlorinated dibenzofurans as contaminants., Formulations, Preparations: The approximate distribution of chlorinated biphenyls in Aroclor 1016 are as follows: <1.0% mono-, 21.2% di-, 51.5% tri-, 27.3% tetra-, <0.6% pentachlorobiphenyl., Aroclor 1016 has an approximate chlorine content of 42%., Aroclor 1016 and Aroclor 1242 are primarily trichlorobiphenyls. The major difference between these two products is the lower penta-, and hexachlorobiphenyl content of Aroclor 1016., U.S. Production:, Production, discontinued in late 1977, General Manufacturing Information: The Aroclors are characterized by four digit numbers. The first two digits indicate that the mixture contains biphenyls (12), triphenyls (54) or both (25, 44), the last two digits give the weight percent of chlorine in the mixture (e.g., Aroclor 1242 contains biphenyls with approximately 42% chlorine)., An exception to, 4 digit with second pair of numbers represent the percentage by weight of chlorine, nomenclature is Aroclor 1016, which contains 40 percent chlorine by weight, Aroclor 1016 was first sold in 1971., When it was determined that there was a significant environmental problem associated with the more heavy chlorinated species, Monsanto prepared a new mixture that was limited primarily to the mono-, di-, and trichloro isomers. This product carried the designation Aroclor 1016., Askarels were often, but not always, a mixture of trichlorobenzenes with PCBs to achieve desired viscosities to permit handling the dielectric as an oily fluid. The capacitor askarels include neat Aroclors 1242, 1254, and 1016 and a mixture of 75% Aroclor 1254 and 25% trichlorobenzene. The most common transformer askarels were 60% Aroclor 1260, 40% trichlorobenzene (Type A) and 70% Aroclor 1254, 30% trichlorobenzene (Type D).
CategoryOrganic Chemicals

Applications

Documented applications: Uses: Although the production and sale was discontinued in late 1977, it is still present in ... capacitors now in use., Chlorinated biphenyls and related compounds, Summary of former end uses for various Aroclors:, Table: Aroclor [Table#5901], PCBs were used as coolants and lubricants in transformers, capacitors, and other electrical devices (such as fluorescent lights and refridgerators) produced before 1977. PCBs may contaminate the air and water near hazardous waste sites. In addition, PCBs bioaccumulate in the environment and may be found in fish, meat, and dairy products. (L4), Methods of Manufacturing: PCBs, were, ... prepared industrially by the chlorination of biphenyl with anhydrous chlorine in the presence of a catalyst such as iron filings or ferric chloride. The products are complex mixtures of chlorobiphenyls, whose degree of chlorination depends principally on the time of contact (12-36 hr) of the biphenyl with anhydrous chlorine. The crude product is blown with air, and a small amount of lime is added to remove hydrogen chloride and ferric chloride. The resulting chlorinated mixtures are batch-distilled to remove color and traces of hydrogen chloride and ferric chloride., Polychlorinated biphenyls, Impurities: Almost without exception, polychlorinated biphenyls contain various levels of polychlorinated dibenzofurans as contaminants., Formulations, Preparations: The approximate distribution of chlorinated biphenyls in Aroclor 1016 are as follows: <1.0% mono-, 21.2% di-, 51.5% tri-, 27.3% tetra-, <0.6% pentachlorobiphenyl., Aroclor 1016 has an approximate chlorine content of 42%., Aroclor 1016 and Aroclor 1242 are primarily trichlorobiphenyls. The major difference between these two products is the lower penta-, and hexachlorobiphenyl content of Aroclor 1016., U.S. Production:, Production, discontinued in late 1977, General Manufacturing Information: The Aroclors are characterized by four digit numbers. The first two digits indicate that the mixture contains biphenyls (12), triphenyls (54) or both (25, 44), the last two digits give the weight percent of chlorine in the mixture (e.g., Aroclor 1242 contains biphenyls with approximately 42% chlorine)., An exception to, 4 digit with second pair of numbers represent the percentage by weight of chlorine, nomenclature is Aroclor 1016, which contains 40 percent chlorine by weight, Aroclor 1016 was first sold in 1971., When it was determined that there was a significant environmental problem associated with the more heavy chlorinated species, Monsanto prepared a new mixture that was limited primarily to the mono-, di-, and trichloro isomers. This product carried the designation Aroclor 1016., Askarels were often, but not always, a mixture of trichlorobenzenes with PCBs to achieve desired viscosities to permit handling the dielectric as an oily fluid. The capacitor askarels include neat Aroclors 1242, 1254, and 1016 and a mixture of 75% Aroclor 1254 and 25% trichlorobenzene. The most common transformer askarels were 60% Aroclor 1260, 40% trichlorobenzene (Type A) and 70% Aroclor 1254, 30% trichlorobenzene (Type D)..

Technical Profile

What this product is

AROCLOR 1016, 1X5ML, TRANSFORMER OIL 50M G/KG is a carbon-based organic compound with CAS registry number 12674-11-2 and molecular formula C12H7Cl3 (molecular weight 257.5), belonging to the organic chemicals segment of chemical raw materials.

Identification

CAS number: 12674-11-2

Its molecular formula C12H7Cl3 comprises 12 C, 7 H, 3 Cl atoms.

Also known as: AROCLOR 1016, 1X5ML, TRANSFORMER OIL 50M G/KG · 亚老哥尔 1016

Category: organic chemicals

Frequently Asked Questions

What is the CAS number of AROCLOR 1016, 1X5ML, TRANSFORMER OIL 50M G/KG?

The CAS registry number of AROCLOR 1016, 1X5ML, TRANSFORMER OIL 50M G/KG is 12674-11-2.

What is the molecular formula and molecular weight of AROCLOR 1016, 1X5ML, TRANSFORMER OIL 50M G/KG?

Molecular formula C12H7Cl3, molecular weight 257.5.

What other names is AROCLOR 1016, 1X5ML, TRANSFORMER OIL 50M G/KG known by?

It is also registered under: AROCLOR 1016, 1X5ML, TRANSFORMER OIL 50M G/KG, 亚老哥尔 1016.

What are the documented applications of AROCLOR 1016, 1X5ML, TRANSFORMER OIL 50M G/KG?

Recorded applications: Uses: Although the production and sale was discontinued in late 1977, it is still present in ... capacitors now in use., Chlorinated biphenyls and related compounds, Summary of former end uses for various Aroclors:, Table: Aroclor [Table#5901], PCBs were used as coolants and lubricants in transformers, capacitors, and other electrical devices (such as fluorescent lights and refridgerators) produced before 1977. PCBs may contaminate the air and water near hazardous waste sites. In addition, PCBs bioaccumulate in the environment and may be found in fish, meat, and dairy products. (L4), Methods of Manufacturing: PCBs, were, ... prepared industrially by the chlorination of biphenyl with anhydrous chlorine in the presence of a catalyst such as iron filings or ferric chloride. The products are complex mixtures of chlorobiphenyls, whose degree of chlorination depends principally on the time of contact (12-36 hr) of the biphenyl with anhydrous chlorine. The crude product is blown with air, and a small amount of lime is added to remove hydrogen chloride and ferric chloride. The resulting chlorinated mixtures are batch-distilled to remove color and traces of hydrogen chloride and ferric chloride., Polychlorinated biphenyls, Impurities: Almost without exception, polychlorinated biphenyls contain various levels of polychlorinated dibenzofurans as contaminants., Formulations, Preparations: The approximate distribution of chlorinated biphenyls in Aroclor 1016 are as follows: <1.0% mono-, 21.2% di-, 51.5% tri-, 27.3% tetra-, <0.6% pentachlorobiphenyl., Aroclor 1016 has an approximate chlorine content of 42%., Aroclor 1016 and Aroclor 1242 are primarily trichlorobiphenyls. The major difference between these two products is the lower penta-, and hexachlorobiphenyl content of Aroclor 1016., U.S. Production:, Production, discontinued in late 1977, General Manufacturing Information: The Aroclors are characterized by four digit numbers. The first two digits indicate that the mixture contains biphenyls (12), triphenyls (54) or both (25, 44), the last two digits give the weight percent of chlorine in the mixture (e.g., Aroclor 1242 contains biphenyls with approximately 42% chlorine)., An exception to, 4 digit with second pair of numbers represent the percentage by weight of chlorine, nomenclature is Aroclor 1016, which contains 40 percent chlorine by weight, Aroclor 1016 was first sold in 1971., When it was determined that there was a significant environmental problem associated with the more heavy chlorinated species, Monsanto prepared a new mixture that was limited primarily to the mono-, di-, and trichloro isomers. This product carried the designation Aroclor 1016., Askarels were often, but not always, a mixture of trichlorobenzenes with PCBs to achieve desired viscosities to permit handling the dielectric as an oily fluid. The capacitor askarels include neat Aroclors 1242, 1254, and 1016 and a mixture of 75% Aroclor 1254 and 25% trichlorobenzene. The most common transformer askarels were 60% Aroclor 1260, 40% trichlorobenzene (Type A) and 70% Aroclor 1254, 30% trichlorobenzene (Type D)..

Which category does AROCLOR 1016, 1X5ML, TRANSFORMER OIL 50M G/KG belong to?

Category: Organic Chemicals.

PubChem Public Data

Independent reference data for AROCLOR 1016, 1X5ML, TRANSFORMER OIL 50M G/KG (CAS 12674-11-2), compiled from public chemistry databases.

Registry identifiers across databases

CAS 号12674-11-2
PubChem CID38037
分子式C12H7Cl3
IUPAC 名称1,3-dichloro-5-(3-chlorophenyl)benzene
UNII(FDA)D998089L9E

Computed descriptors

Molecular Weight257.5
XLogP35.8
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count0
Rotatable Bond Count1
Exact Mass255.961333
Monoisotopic Mass255.961333
Topological Polar Surface Area0
Heavy Atom Count15

Physicochemical values on record

Boiling Point725 to 788 °F at 760 mmHg (NTP, 1992)
Flash Point286 °F (NTP, 1992)
SolubilityIn water: 0.085 ppm
SolubilityIn water, 0.42 mg/L at 25 °C
Density1.33 g/mL at 25 °C
Density1.44 @ 30°C
Vapor Pressure4X10-4 mm Hg at 25 °C
LogPlog Kow = 4.38
LogP5.81
Viscosity71-81 Saybolt sec at 37.8 °C

Synonyms and trade names

3,3',5-TRICHLOROBIPHENYL; 38444-87-0; 3,3',5-Trichloro-1,1'-biphenyl; PCB 36; 1,1'-Biphenyl, 3,3',5-trichloro-; UNII-D998089L9E; D998089L9E; DTXSID50858937; RefChem:53619; DTXCID503883; AROCLOR 1016; 12674-11-2; Arochlor 1016; 1,3-dichloro-5-(3-chlorophenyl)benzene; aroclor-1016; Chlorodiphenyl (41% Cl)

Regulatory listings held on file

GHS 通报统计2.4% (1 / 42)

GHS hazard classification

GHS 通报统计2.4% (1 / 42)
已通报的危害声明H373 (97.6%), H400 (97.6%), H410 (97.6%)

What the public record says

亚老哥尔 1016 · CAS 12674-11-2 · C12H7Cl3。 UNII D998089L9E。沸点:760 mmHg 时 725 至 788 °F(NTP,1992);闪点:286°F(NTP,1992);溶解度:水中:0.085 ppm。

Source: PubChem / Wikidata; the batch COA governs where values differ.

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