2-Hydroxypropyl methacrylate, mixture of isomers (CAS 27813-02-1) — formula C7H12O3, molecular weight 144.17; category organic chemicals.
| CAS Number | 27813-02-1 |
|---|---|
| Molecular Formula | C7H12O3 |
| Molecular Weight | 144.17 |
| Melting Point | -89 °C |
| LogP | 1.2 |
| Applications | Uses: CIR ingredient: Hydroxypropyl Methacrylate, Used as monomer (i.e. acrylic resins, nonwoven fabric binders, and detergent lube oil additives) and in elastomers, laminating resins, and dental filling materials, [HSDB], Textiles (Fiber & Fabric Manufacturing) [Category: Industry], Plastic Composites Manufacturing [Category: Industry], COMONOMER IN CROSS-LINKED-THERMOSET-ACRYLIC COATING RESINS, FOR ELASTOMERS, FOR LAMINATING RESINS, MONOMER FOR NONWOVEN FABRIC BINDER, IN DENTAL FILLING MATERIAL, Monomer for acrylic resins, detergent lube oil additives, Industry Uses: Monomers, Polymerization promoter, Surface modifier, Intermediate, Hardener, Photosensitive chemicals, Sealant (barrier), Impregnation agent, Consumer Uses: Binder, Diluent, Household Products: Information on 1 consumer products that contain Hydroxyalkyl methacrylate in the following categories is provided:, • Home Maintenance, Methods of Manufacturing: ADDITION OF PROPYLENE OXIDE TO METHACRYLIC ACID WITH A BASE AS CATALYST, Hydroxyalkyl methacrylates are prepared by the addition of methacrylic acid to the epoxide ring of alkylene oxides to form hydroxyalkyl methacrylates, ie, beta-hydroxyethyl and hydroxypropyl methacrylate. Oxides other than ethylene oxide give isomeric products, commercial hydroxypropyl methyacrylate has about a 2-to-1 ratio of 2-hydroxypropyl methacrylate to 1-methyl-2-hydroxyethyl methacrylate. Effective catalysts include tertiary amines, anion-exchange resins, ferric chloride, and lithium methacrylate., The methacrylates can be synthesized by catalytic oxidation of isobutylene and subsequent esterification with the appropriate alcohol, or by reacting acetone with hydrocyanic acid and subsequent esterification in sulfuric acid with the appropriate alcohol., Methacrylic esters, Formulations, Preparations: Inhibitior of polymerization: 200 ppm hydroquinone, Grades of purity: Commercial, 95+%, Typical inhibitor level: 1200 ppm monomethyl ether hydroquinone, Consumption Patterns: 100% AS MONOMER, U.S. Production: 2023: 5, 500, 000 - <7, 000, 000 lb, 2022: 5, 2021: 5, 2020: 5, General Manufacturing Information: Electrical Equipment, Appliance, and Component Manufacturing, Petroleum Lubricating Oil and Grease Manufacturing, Transportation Equipment Manufacturing, Plastics Product Manufacturing, Computer and Electronic Product Manufacturing, Custom Compounding of Purchased Resins, Miscellaneous Manufacturing, Machinery Manufacturing, Fabricated Metal Product Manufacturing, Plastics Material and Resin Manufacturing, Paint and Coating Manufacturing, Adhesive Manufacturing, All Other Chemical Product and Preparation Manufacturing, 2-Propenoic acid, 2-methyl-, monoester with 1, 2-propanediol: ACTIVE, METHYL METHACRYLATE, AND IN GENERAL THE METHACRYLIC ESTERS, POLYMERIZE MUCH LESS READILY THAN THE CORRESPONDING ORDINARY ACRYLATES. NONE THE LESS, THEY ARE STABILIZED BY ADDING HYDROQUINONE OR PYROGALLOL, PARTICULARLY IN THE PRESENCE OF METALLIC COPPER., METHACRYLATES |
| Category | Organic Chemicals |
Documented applications: Uses: CIR ingredient: Hydroxypropyl Methacrylate, Used as monomer (i.e. acrylic resins, nonwoven fabric binders, and detergent lube oil additives) and in elastomers, laminating resins, and dental filling materials, [HSDB], Textiles (Fiber & Fabric Manufacturing) [Category: Industry], Plastic Composites Manufacturing [Category: Industry], COMONOMER IN CROSS-LINKED-THERMOSET-ACRYLIC COATING RESINS, FOR ELASTOMERS, FOR LAMINATING RESINS, MONOMER FOR NONWOVEN FABRIC BINDER, IN DENTAL FILLING MATERIAL, Monomer for acrylic resins, detergent lube oil additives, Industry Uses: Monomers, Polymerization promoter, Surface modifier, Intermediate, Hardener, Photosensitive chemicals, Sealant (barrier), Impregnation agent, Consumer Uses: Binder, Diluent, Household Products: Information on 1 consumer products that contain Hydroxyalkyl methacrylate in the following categories is provided:, • Home Maintenance, Methods of Manufacturing: ADDITION OF PROPYLENE OXIDE TO METHACRYLIC ACID WITH A BASE AS CATALYST, Hydroxyalkyl methacrylates are prepared by the addition of methacrylic acid to the epoxide ring of alkylene oxides to form hydroxyalkyl methacrylates, ie, beta-hydroxyethyl and hydroxypropyl methacrylate. Oxides other than ethylene oxide give isomeric products, commercial hydroxypropyl methyacrylate has about a 2-to-1 ratio of 2-hydroxypropyl methacrylate to 1-methyl-2-hydroxyethyl methacrylate. Effective catalysts include tertiary amines, anion-exchange resins, ferric chloride, and lithium methacrylate., The methacrylates can be synthesized by catalytic oxidation of isobutylene and subsequent esterification with the appropriate alcohol, or by reacting acetone with hydrocyanic acid and subsequent esterification in sulfuric acid with the appropriate alcohol., Methacrylic esters, Formulations, Preparations: Inhibitior of polymerization: 200 ppm hydroquinone, Grades of purity: Commercial, 95+%, Typical inhibitor level: 1200 ppm monomethyl ether hydroquinone, Consumption Patterns: 100% AS MONOMER, U.S. Production: 2023: 5, 500, 000 - <7, 000, 000 lb, 2022: 5, 2021: 5, 2020: 5, General Manufacturing Information: Electrical Equipment, Appliance, and Component Manufacturing, Petroleum Lubricating Oil and Grease Manufacturing, Transportation Equipment Manufacturing, Plastics Product Manufacturing, Computer and Electronic Product Manufacturing, Custom Compounding of Purchased Resins, Miscellaneous Manufacturing, Machinery Manufacturing, Fabricated Metal Product Manufacturing, Plastics Material and Resin Manufacturing, Paint and Coating Manufacturing, Adhesive Manufacturing, All Other Chemical Product and Preparation Manufacturing, 2-Propenoic acid, 2-methyl-, monoester with 1, 2-propanediol: ACTIVE, METHYL METHACRYLATE, AND IN GENERAL THE METHACRYLIC ESTERS, POLYMERIZE MUCH LESS READILY THAN THE CORRESPONDING ORDINARY ACRYLATES. NONE THE LESS, THEY ARE STABILIZED BY ADDING HYDROQUINONE OR PYROGALLOL, PARTICULARLY IN THE PRESENCE OF METALLIC COPPER., METHACRYLATES.
2-Hydroxypropyl methacrylate, mixture of isomers is a carbon-based organic compound with CAS registry number 27813-02-1 and molecular formula C7H12O3 (molecular weight 144.17), belonging to the organic chemicals segment of chemical raw materials.
CAS number: 27813-02-1
Its molecular formula C7H12O3 comprises 7 C, 12 H, 3 O atoms.
Also known as: 2-Hydroxypropyl methacrylate, mixture of isomers · 甲基丙烯酸 2-羟丙酯，异构体混合物
Category: organic chemicals
The CAS registry number of 2-Hydroxypropyl methacrylate, mixture of isomers is 27813-02-1.
Molecular formula C7H12O3, molecular weight 144.17.
It is also registered under: 2-Hydroxypropyl methacrylate, mixture of isomers, 甲基丙烯酸 2-羟丙酯，异构体混合物.
Recorded applications: Uses: CIR ingredient: Hydroxypropyl Methacrylate, Used as monomer (i.e. acrylic resins, nonwoven fabric binders, and detergent lube oil additives) and in elastomers, laminating resins, and dental filling materials, [HSDB], Textiles (Fiber & Fabric Manufacturing) [Category: Industry], Plastic Composites Manufacturing [Category: Industry], COMONOMER IN CROSS-LINKED-THERMOSET-ACRYLIC COATING RESINS, FOR ELASTOMERS, FOR LAMINATING RESINS, MONOMER FOR NONWOVEN FABRIC BINDER, IN DENTAL FILLING MATERIAL, Monomer for acrylic resins, detergent lube oil additives, Industry Uses: Monomers, Polymerization promoter, Surface modifier, Intermediate, Hardener, Photosensitive chemicals, Sealant (barrier), Impregnation agent, Consumer Uses: Binder, Diluent, Household Products: Information on 1 consumer products that contain Hydroxyalkyl methacrylate in the following categories is provided:, • Home Maintenance, Methods of Manufacturing: ADDITION OF PROPYLENE OXIDE TO METHACRYLIC ACID WITH A BASE AS CATALYST, Hydroxyalkyl methacrylates are prepared by the addition of methacrylic acid to the epoxide ring of alkylene oxides to form hydroxyalkyl methacrylates, ie, beta-hydroxyethyl and hydroxypropyl methacrylate. Oxides other than ethylene oxide give isomeric products, commercial hydroxypropyl methyacrylate has about a 2-to-1 ratio of 2-hydroxypropyl methacrylate to 1-methyl-2-hydroxyethyl methacrylate. Effective catalysts include tertiary amines, anion-exchange resins, ferric chloride, and lithium methacrylate., The methacrylates can be synthesized by catalytic oxidation of isobutylene and subsequent esterification with the appropriate alcohol, or by reacting acetone with hydrocyanic acid and subsequent esterification in sulfuric acid with the appropriate alcohol., Methacrylic esters, Formulations, Preparations: Inhibitior of polymerization: 200 ppm hydroquinone, Grades of purity: Commercial, 95+%, Typical inhibitor level: 1200 ppm monomethyl ether hydroquinone, Consumption Patterns: 100% AS MONOMER, U.S. Production: 2023: 5, 500, 000 - <7, 000, 000 lb, 2022: 5, 2021: 5, 2020: 5, General Manufacturing Information: Electrical Equipment, Appliance, and Component Manufacturing, Petroleum Lubricating Oil and Grease Manufacturing, Transportation Equipment Manufacturing, Plastics Product Manufacturing, Computer and Electronic Product Manufacturing, Custom Compounding of Purchased Resins, Miscellaneous Manufacturing, Machinery Manufacturing, Fabricated Metal Product Manufacturing, Plastics Material and Resin Manufacturing, Paint and Coating Manufacturing, Adhesive Manufacturing, All Other Chemical Product and Preparation Manufacturing, 2-Propenoic acid, 2-methyl-, monoester with 1, 2-propanediol: ACTIVE, METHYL METHACRYLATE, AND IN GENERAL THE METHACRYLIC ESTERS, POLYMERIZE MUCH LESS READILY THAN THE CORRESPONDING ORDINARY ACRYLATES. NONE THE LESS, THEY ARE STABILIZED BY ADDING HYDROQUINONE OR PYROGALLOL, PARTICULARLY IN THE PRESENCE OF METALLIC COPPER., METHACRYLATES.
Category: Organic Chemicals.
Independent reference data for 2-Hydroxypropyl methacrylate, mixture of isomers (CAS 27813-02-1), compiled from public chemistry databases.
| CAS Registry Number | 27813-02-1 |
|---|---|
| PubChem CID | 34023 |
| Molecular formula | C7H12O3 |
| IUPAC name | 1-hydroxypropan-2-yl 2-methylprop-2-enoate |
| UNII (FDA) | BC693EJ6V3 |
| Molecular Weight | 144.17 |
|---|---|
| XLogP3 | 1.2 |
| Hydrogen Bond Donor Count | 1 |
| Hydrogen Bond Acceptor Count | 3 |
| Rotatable Bond Count | 4 |
| Exact Mass | 144.078644241 |
| Monoisotopic Mass | 144.078644241 |
| Topological Polar Surface Area | 46.5 |
| Heavy Atom Count | 10 |
| Melting Point | -89 °C |
|---|---|
| Flash Point | 250 °F (USCG, 1999) |
| Density | 1.066 @ 25 °C/16 °C |
| Vapor Pressure | 0.02 [mmHg] |
Rocryl 410; 1,2-Propanediol, monomethacrylate; UKW89XAX2X; 1,2-Propanediol, 2-methyl, monomethacrylate; Methacrylic acid, monoester with 1,2-propanediol; 2-Propenoic acid, 2-methyl-, 2-hydroxymethylethyl ester; DTXSID5027936; RefChem:923164; DTXCID301778493; 248-666-3; 2-Propenoic acid, 2-methyl-, monoester with 1,2-propanediol; 27813-02-1; HPMA; Hydroxypropyl Methacrylate; Propylene glycol monomethacrylate; 2-Hydroxy-1-methylethyl methacrylate
| Regulatory & Food Contact | FDA Inventory of Food Contact Substances Listed in 21 CFR: FCS CIR / INCI: Cosmetic ingredients (Hydroxypropyl Methacrylate) -> CIR (Cosmetic Ingredient Review) |
|---|---|
| GHS notification summary | 0.8% (12 / 1419) |
| GHS notification summary | 0.8% (12 / 1419) |
|---|---|
| Reported hazard statements | H317 (97%), H319 (96.4%) |
This chemical does not meet GHS hazard criteria for 0.8% (12 of 1419) of reports.
H317 (97%): May cause an allergic skin reaction [Warning Sensitization, Skin]
2-Hydroxypropyl methacrylate, mixture of isomers · CAS 27813-02-1 · C7H12O3. UNII BC693EJ6V3. Melting Point: -89 °C; Flash Point: 250 °F (USCG, 1999); Density: 1.066 @ 25 °C/16 °C.
Source: PubChem / Wikidata; the batch COA governs where values differ.
Supplier: Jinan Shenghe Chemical Co., Ltd.
中文页面: 甲基丙烯酸 2-羟丙酯，异构体混合物