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2-Chloroethyl phosphoric acid

CAS 16672-87-0C2H6ClO3PMW 144.49

2-Chloroethyl phosphoric acid (CAS 16672-87-0) — formula C2H6ClO3P, molecular weight 144.49; category organic chemicals.

Product Overview

CAS Number16672-87-0
Molecular FormulaC2H6ClO3P
Molecular Weight144.49
Melting Point74-75 °C
Boiling Point265 °C (decomposes)
LogPlog Kow = -0.22
ApplicationsUses: Used as plant growth regulator to promote ripening in fruits, nuts, and other crops and to stimulate latex flow in rubber, [HSDB] Used primarily on cotton, [Reference #1], Farming (Pesticides) [Category: Industry], For ethephon (USEPA, OPP Pesticide Code: 099801) ACTIVE products with label matches., SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses., A plant-growth regulator that increases rate of ripening of plants by promoting release of ethylene, stimulates rubber latex formation, ripening of sugarcane, flowering agent for pineapple, color enhancer., In cotton, it is used as a boll opener and defoliant prior to harvesting., Ethephon is used to promote fruit ripening, abscission, flower induction, breaking of apical dominance (inhibition of the growth of lateral buds by the terminal bud of a shoot), and other plant responses., This is a man-made compound that is used as a pesticide., Use Classification: Environmental transformation -> Pesticides (parent, predecessor), Plant growth regulators, Methods of Manufacturing: CLEAVAGE OF THE BIS(2-CHLOROETHYL) ESTER OF 2-CHLOROETHYL PHOSPHONIC ACID, Ethephon is made from tris(2-chloroethyl) phosphite by rearrangement to bis(2-chloroethyl)2-chloroethyl phosphonate followed by hydrolysis, Formulations, Preparations: Aqueous solutions, liquid concentrate., Premix Partners: AMADS, chlormequat chloride, cyclanilide, mepiquat chloride., Emulsifiable concentrate, suspension concentrate (flowable concentrate), soluble concentrate., First Pick Cotton Harvest Aid, Defoliant (Nufarm Americas Inc): Ethephon 18.3%, Sulfuric acid, monourea adduct 58.6%., For more Formulations, Preparations (Complete) data for ETHEPHON (44 total), please visit the HSDB record page., Consumption Patterns: On average about 4.1 million pounds of ethephon are used annually on 1.7 million acres. The crops with highest percent crop treated are tart cherries (61%), grapes (40%), processed tomatoes (15%), and cotton (10%)., U.S. Production: (1972) PROBABLY GREATER THAN 4.54X10+5 GRAMS, (1975) PROBABLY GREATER THAN 4.54X10+5 GRAMS, General Manufacturing Information: The WHO Recommended Classification of Pesticides by Hazard identifies ethephon (technical grade) as Class III: slightly hazardous, Main Use: plant growth regulator., ETHEPHON SPRAY ON TOMATO TRANSPLANTS (LYCOPERSICON ESCULENTUM) 12 DAYS PRIOR TO PULLING RESULTED IN PARTIAL PROTECTION OF THE PLANTS FROM FROST INJURY AFTER TRANSPLANTING., ... Ethephon is an organophosphonate as opposed to an organophosphate. It is structurally different from and exhibits different physical, chemical properties than traditional organophosphate compounds. The toxicological profile of ethephon also differs from that of the organophosphate compounds.
CategoryOrganic Chemicals

Applications

Documented applications: Uses: Used as plant growth regulator to promote ripening in fruits, nuts, and other crops and to stimulate latex flow in rubber, [HSDB] Used primarily on cotton, [Reference #1], Farming (Pesticides) [Category: Industry], For ethephon (USEPA, OPP Pesticide Code: 099801) ACTIVE products with label matches., SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses., A plant-growth regulator that increases rate of ripening of plants by promoting release of ethylene, stimulates rubber latex formation, ripening of sugarcane, flowering agent for pineapple, color enhancer., In cotton, it is used as a boll opener and defoliant prior to harvesting., Ethephon is used to promote fruit ripening, abscission, flower induction, breaking of apical dominance (inhibition of the growth of lateral buds by the terminal bud of a shoot), and other plant responses., This is a man-made compound that is used as a pesticide., Use Classification: Environmental transformation -> Pesticides (parent, predecessor), Plant growth regulators, Methods of Manufacturing: CLEAVAGE OF THE BIS(2-CHLOROETHYL) ESTER OF 2-CHLOROETHYL PHOSPHONIC ACID, Ethephon is made from tris(2-chloroethyl) phosphite by rearrangement to bis(2-chloroethyl)2-chloroethyl phosphonate followed by hydrolysis, Formulations, Preparations: Aqueous solutions, liquid concentrate., Premix Partners: AMADS, chlormequat chloride, cyclanilide, mepiquat chloride., Emulsifiable concentrate, suspension concentrate (flowable concentrate), soluble concentrate., First Pick Cotton Harvest Aid, Defoliant (Nufarm Americas Inc): Ethephon 18.3%, Sulfuric acid, monourea adduct 58.6%., For more Formulations, Preparations (Complete) data for ETHEPHON (44 total), please visit the HSDB record page., Consumption Patterns: On average about 4.1 million pounds of ethephon are used annually on 1.7 million acres. The crops with highest percent crop treated are tart cherries (61%), grapes (40%), processed tomatoes (15%), and cotton (10%)., U.S. Production: (1972) PROBABLY GREATER THAN 4.54X10+5 GRAMS, (1975) PROBABLY GREATER THAN 4.54X10+5 GRAMS, General Manufacturing Information: The WHO Recommended Classification of Pesticides by Hazard identifies ethephon (technical grade) as Class III: slightly hazardous, Main Use: plant growth regulator., ETHEPHON SPRAY ON TOMATO TRANSPLANTS (LYCOPERSICON ESCULENTUM) 12 DAYS PRIOR TO PULLING RESULTED IN PARTIAL PROTECTION OF THE PLANTS FROM FROST INJURY AFTER TRANSPLANTING., ... Ethephon is an organophosphonate as opposed to an organophosphate. It is structurally different from and exhibits different physical, chemical properties than traditional organophosphate compounds. The toxicological profile of ethephon also differs from that of the organophosphate compounds..

Technical Profile

What this product is

2-Chloroethyl phosphoric acid is a carbon-based organic compound with CAS registry number 16672-87-0 and molecular formula C2H6ClO3P (molecular weight 144.49), belonging to the organic chemicals segment of chemical raw materials.

Identification

CAS number: 16672-87-0

Its molecular formula C2H6ClO3P comprises 2 C, 6 H, 1 Cl, 3 O, 1 P atoms.

Also known as: 2-Chloroethyl phosphoric acid · 2-氯乙基磷酸

Category: organic chemicals

Frequently Asked Questions

What is the CAS number of 2-Chloroethyl phosphoric acid?

The CAS registry number of 2-Chloroethyl phosphoric acid is 16672-87-0.

What is the molecular formula and molecular weight of 2-Chloroethyl phosphoric acid?

Molecular formula C2H6ClO3P, molecular weight 144.49.

What other names is 2-Chloroethyl phosphoric acid known by?

It is also registered under: 2-Chloroethyl phosphoric acid, 2-氯乙基磷酸.

What are the documented applications of 2-Chloroethyl phosphoric acid?

Recorded applications: Uses: Used as plant growth regulator to promote ripening in fruits, nuts, and other crops and to stimulate latex flow in rubber, [HSDB] Used primarily on cotton, [Reference #1], Farming (Pesticides) [Category: Industry], For ethephon (USEPA, OPP Pesticide Code: 099801) ACTIVE products with label matches., SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses., A plant-growth regulator that increases rate of ripening of plants by promoting release of ethylene, stimulates rubber latex formation, ripening of sugarcane, flowering agent for pineapple, color enhancer., In cotton, it is used as a boll opener and defoliant prior to harvesting., Ethephon is used to promote fruit ripening, abscission, flower induction, breaking of apical dominance (inhibition of the growth of lateral buds by the terminal bud of a shoot), and other plant responses., This is a man-made compound that is used as a pesticide., Use Classification: Environmental transformation -> Pesticides (parent, predecessor), Plant growth regulators, Methods of Manufacturing: CLEAVAGE OF THE BIS(2-CHLOROETHYL) ESTER OF 2-CHLOROETHYL PHOSPHONIC ACID, Ethephon is made from tris(2-chloroethyl) phosphite by rearrangement to bis(2-chloroethyl)2-chloroethyl phosphonate followed by hydrolysis, Formulations, Preparations: Aqueous solutions, liquid concentrate., Premix Partners: AMADS, chlormequat chloride, cyclanilide, mepiquat chloride., Emulsifiable concentrate, suspension concentrate (flowable concentrate), soluble concentrate., First Pick Cotton Harvest Aid, Defoliant (Nufarm Americas Inc): Ethephon 18.3%, Sulfuric acid, monourea adduct 58.6%., For more Formulations, Preparations (Complete) data for ETHEPHON (44 total), please visit the HSDB record page., Consumption Patterns: On average about 4.1 million pounds of ethephon are used annually on 1.7 million acres. The crops with highest percent crop treated are tart cherries (61%), grapes (40%), processed tomatoes (15%), and cotton (10%)., U.S. Production: (1972) PROBABLY GREATER THAN 4.54X10+5 GRAMS, (1975) PROBABLY GREATER THAN 4.54X10+5 GRAMS, General Manufacturing Information: The WHO Recommended Classification of Pesticides by Hazard identifies ethephon (technical grade) as Class III: slightly hazardous, Main Use: plant growth regulator., ETHEPHON SPRAY ON TOMATO TRANSPLANTS (LYCOPERSICON ESCULENTUM) 12 DAYS PRIOR TO PULLING RESULTED IN PARTIAL PROTECTION OF THE PLANTS FROM FROST INJURY AFTER TRANSPLANTING., ... Ethephon is an organophosphonate as opposed to an organophosphate. It is structurally different from and exhibits different physical, chemical properties than traditional organophosphate compounds. The toxicological profile of ethephon also differs from that of the organophosphate compounds..

Which category does 2-Chloroethyl phosphoric acid belong to?

Category: Organic Chemicals.

PubChem Public Data

Independent reference data for 2-Chloroethyl phosphoric acid (CAS 16672-87-0), compiled from public chemistry databases.

Registry identifiers across databases

CAS Registry Number16672-87-0
PubChem CID27982
Molecular formulaC2H6ClO3P
IUPAC name2-chloroethylphosphonic acid
UNII (FDA)XU5R5VQ87S

Computed descriptors

Molecular Weight144.49
XLogP3-1
Hydrogen Bond Donor Count2
Hydrogen Bond Acceptor Count3
Rotatable Bond Count2
Exact Mass143.9743087
Monoisotopic Mass143.9743087
Topological Polar Surface Area57.5
Heavy Atom Count7

Physicochemical values on record

Boiling Point265 °C (decomposes)
Melting Point74-75 °C
Density1.2 g/cu cm
Vapor Pressure0.0000001 [mmHg]
Vapor Pressure< 7.5X10-8 mm Hg at 20 °C
LogPlog Kow = -0.22

Documented uses on record

    Used as plant growth regulator to promote ripening in fruits, nuts, and other crops and to stimulate latex flow in rubber; [HSDB] Used primarily on cotton; [Reference #1]A plant-growth regulator that increases rate of ripening of plants by promoting release of ethylene, stimulates rubber latex formation; ripening of sugarcane; flowering agent for pineapple; color enhancer.

    Synonyms and trade names

    ETHEPHON; 16672-87-0; 2-Chloroethylphosphonic acid; (2-Chloroethyl)phosphonic acid; Ethrel; Bromeflor; Camposan; Cerone; 2-Cepa; Ethefon; Etheverse; Flordimex; Kamposan; Tomathrel; Cepha; Ethel

    GHS hazard classification

    Reported hazard statementsH302, H311, H314, H332, H411, H312 (32.3%), H318 (66.2%), H412 (32.3%)

    H302: Harmful if swallowed [Warning Acute toxicity, oral]

    H311: Toxic in contact with skin [Danger Acute toxicity, dermal]

    What the public record says

    2-Chloroethyl phosphoric acid · CAS 16672-87-0 · C2H6ClO3P. UNII XU5R5VQ87S. Boiling Point: 265 °C (decomposes); Melting Point: 74-75 °C; Density: 1.2 g/cu cm.

    Physical description and handling notes

    Source: PubChem / Wikidata; the batch COA governs where values differ.

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