Metham-Sodium（CAS 137-42-8）：分子式 C2H4NNaS2、分子量 129.18；类别 无机化学品。
| CAS号 | 137-42-8 |
|---|---|
| 分子式 | C2H4NNaS2 |
| 分子量 | 129.18 |
| LogP | log Kow <1 at 25 °C |
| 应用领域 | Uses: Used as a fungicide and nematicide、[Kanerva、p. 1834] Used as a soil fumigant for control of weeds、weed seeds、nematodes、fungi、and soil insects、[Merck Index] Used as non-selective soil fumigant that possesses fungicidal、herbicidal、insecticidal、and nematicidal properties、Approved for use on food、feed、and fiber crops、turf grass、sewers、and drained ponds and lakes (California only)、Also used as antimicrobial agent for wood poles、leather processing、sugar cane and beet processing、sewage sludge、and animal waste、[Reference #2] Approved for use in the EU as a pre-plant soil disinfectant for vegetables、fruit trees、grape vines、nurseries、ornamentals、and other crops、[EFSA]、Restricted use pesticide for application on golf courses、small areas of turf and soil、and in sewers and drains、[Reference #2]、Applying Wood Preservatives [Category: Other]、Farming (Pesticides) [Category: Industry]、Sewer and Wastewater Treatment [Category: Industry]、Leather Tanning and Processing [Category: Industry]、For Sodium Methyldithiocarbamate (USEPA、OPP Pesticide Code: 039003) ACTIVE products with label matches.、SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal、state and local authorities must be consulted for currently approved uses.、Metam-sodium and metam-potassium are broad spectrum fumigants with fungicidal、bactericidal、algaecide、nematicidal、and antimicrobial properties. They are dithiocarbamate salts that break down quickly in the environment to the primary toxic degradate、methyl isothiocyanate (MITC). MITC is highly volatile and is responsible for the fumigant properties of metam-sodium and metam-potassium.、Restricted Use Pesticide (RUP) Classification. MITC、the byproduct of metam sodium、metam potassium、and dazomet、meets the criteria for restricted use based on human hazard criteria and exposure incidents. All soil fumigant products containing metam sodium or metam potassium will be RUPs.、Soil fumigant to control weeds and weed seeds、amd soil insects、For more Uses (Complete) data for SODIUM METHYLDITHIOCARBAMATE (11 total)、please visit the HSDB record page.、Use Classification: SOIL FUNGICIDES、Methods of Manufacturing:、It is、prepared from methylamine、carbon disulfide and sodium hydroxide、From methyl isothiocyanate and sodium bisulfide.、Metam sodium is produced by reaction of methylamine with carbon disulfide and sodium hydroxide.、Formulations、Preparations: Soluble concentrates、aqueous solutions.、... Since、pure metham、is unstable、the commercial formulation (Vapam) is always kept as a concentrated 32.7% solution in water.、Trade Names ... Metam 426、Polefume、Turfcure、Vapam、Vapam HL、Busan 1236、Nemasol、Metam CLR、Sectagon 42、Sistan、Meter、Soldier、Basamid liquid (aq formulation containing 45% methylcarbamodithionic acid monosodium salt as ai)、Metam-Fluid (aq formulation containing 42.2% methylcarbamodithionic acid monosodium salt as ai)、VAPAM technical (technical formulation containing 32.9% methylcarbamodithionic acid monosodium salt as ai)、For more Formulations、Preparations (Complete) data for SODIUM METHYLDITHIOCARBAMATE (37 total)、Consumption Patterns: Approximately 51-55 million pounds of metam-sodium and 1-2 million pounds of metam-potassium used in the U.S. in 2002.、U.S. Production: Carbamodithioic acid、methyl-、monosodium salt is listed as a High Production Volume (HPV) chemical (65FR81686). Chemicals listed as HPV were produced in or imported into the U.S. in >1 million pounds in 1990 and、or 1994. The HPV list is based on the 1990 Inventory Update Rule. (IUR) (40 CFR part 710 subpart B、51FR21438).、General Manufacturing Information: The WHO Recommended Classification of Pesticides by Hazard identifies Metam-sodium (technical grade) as Class II: moderately hazardous、Main Use: fungicide-applied to soil: not used with herbicides or plant growth regulators.、The、USEPA、has determined that certain uses of (1) metam sodium (including use as a pre-plant soil fumigant in certain crops、specified、in the R.E.D.、and as a root control agent in sewers and drains、and as an antimicrobial agent to treat wood poles and timbers and sewage sludge and animal waste)、(2) metam-potassium (including as a pre-plant soil fumigant in certain crops、specified later in this document、and as an antimicrobial agent for treatment of pulp and paper、tanning drum leather applications、recirculating cooling water systems、and industrial water purification systems)、and (3) MITC (as an antimicrobial agent to treat wood poles and pilings) are eligible for reregistration、provided the risk mitigation measures outlined in、the R.E.D.、are adopted、label amendments are made to reflect these measures ...、and data are developed to assess intermediate- and long-term risk to bystanders.、Metham-sodium was introduced by Stauffer Chemical Company & later by EI du Pont de Nemours & Company、Inc、& ICI Plant Protection Division (neither of whom now market it). US patents 2、766、554、2、791、605、GBP、British patent、789、690 all Stauffer Chemical Company as code number N-869 (Stauffer)、trade marks Vapam (Stauffer)、VPM (formerly du Pont)、Sistan (ICI).、...、Metham sodium gives、a complete kill of root knot nematodes in sandy soil at 5 ppm. It is an effective non-selective herbicide at rates of ... 200 lb、acre. ... it is particularly effective in cracks & under walks where the methyl isothiocyanate is confined.、For more General Manufacturing Information (Complete) data for SODIUM METHYLDITHIOCARBAMATE (11 total) |
| 类别 | Inorganic Chemicals |
登记用途：Uses: Used as a fungicide and nematicide、[Kanerva、p. 1834] Used as a soil fumigant for control of weeds、weed seeds、nematodes、fungi、and soil insects、[Merck Index] Used as non-selective soil fumigant that possesses fungicidal、herbicidal、insecticidal、and nematicidal properties、Approved for use on food、feed、and fiber crops、turf grass、sewers、and drained ponds and lakes (California only)、Also used as antimicrobial agent for wood poles、leather processing、sugar cane and beet processing、sewage sludge、and animal waste、[Reference #2] Approved for use in the EU as a pre-plant soil disinfectant for vegetables、fruit trees、grape vines、nurseries、ornamentals、and other crops、[EFSA]、Restricted use pesticide for application on golf courses、small areas of turf and soil、and in sewers and drains、[Reference #2]、Applying Wood Preservatives [Category: Other]、Farming (Pesticides) [Category: Industry]、Sewer and Wastewater Treatment [Category: Industry]、Leather Tanning and Processing [Category: Industry]、For Sodium Methyldithiocarbamate (USEPA、OPP Pesticide Code: 039003) ACTIVE products with label matches.、SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal、state and local authorities must be consulted for currently approved uses.、Metam-sodium and metam-potassium are broad spectrum fumigants with fungicidal、bactericidal、algaecide、nematicidal、and antimicrobial properties. They are dithiocarbamate salts that break down quickly in the environment to the primary toxic degradate、methyl isothiocyanate (MITC). MITC is highly volatile and is responsible for the fumigant properties of metam-sodium and metam-potassium.、Restricted Use Pesticide (RUP) Classification. MITC、the byproduct of metam sodium、metam potassium、and dazomet、meets the criteria for restricted use based on human hazard criteria and exposure incidents. All soil fumigant products containing metam sodium or metam potassium will be RUPs.、Soil fumigant to control weeds and weed seeds、amd soil insects、For more Uses (Complete) data for SODIUM METHYLDITHIOCARBAMATE (11 total)、please visit the HSDB record page.、Use Classification: SOIL FUNGICIDES、Methods of Manufacturing:、It is、prepared from methylamine、carbon disulfide and sodium hydroxide、From methyl isothiocyanate and sodium bisulfide.、Metam sodium is produced by reaction of methylamine with carbon disulfide and sodium hydroxide.、Formulations、Preparations: Soluble concentrates、aqueous solutions.、... Since、pure metham、is unstable、the commercial formulation (Vapam) is always kept as a concentrated 32.7% solution in water.、Trade Names ... Metam 426、Polefume、Turfcure、Vapam、Vapam HL、Busan 1236、Nemasol、Metam CLR、Sectagon 42、Sistan、Meter、Soldier、Basamid liquid (aq formulation containing 45% methylcarbamodithionic acid monosodium salt as ai)、Metam-Fluid (aq formulation containing 42.2% methylcarbamodithionic acid monosodium salt as ai)、VAPAM technical (technical formulation containing 32.9% methylcarbamodithionic acid monosodium salt as ai)、For more Formulations、Preparations (Complete) data for SODIUM METHYLDITHIOCARBAMATE (37 total)、Consumption Patterns: Approximately 51-55 million pounds of metam-sodium and 1-2 million pounds of metam-potassium used in the U.S. in 2002.、U.S. Production: Carbamodithioic acid、methyl-、monosodium salt is listed as a High Production Volume (HPV) chemical (65FR81686). Chemicals listed as HPV were produced in or imported into the U.S. in >1 million pounds in 1990 and、or 1994. The HPV list is based on the 1990 Inventory Update Rule. (IUR) (40 CFR part 710 subpart B、51FR21438).、General Manufacturing Information: The WHO Recommended Classification of Pesticides by Hazard identifies Metam-sodium (technical grade) as Class II: moderately hazardous、Main Use: fungicide-applied to soil: not used with herbicides or plant growth regulators.、The、USEPA、has determined that certain uses of (1) metam sodium (including use as a pre-plant soil fumigant in certain crops、specified、in the R.E.D.、and as a root control agent in sewers and drains、and as an antimicrobial agent to treat wood poles and timbers and sewage sludge and animal waste)、(2) metam-potassium (including as a pre-plant soil fumigant in certain crops、specified later in this document、and as an antimicrobial agent for treatment of pulp and paper、tanning drum leather applications、recirculating cooling water systems、and industrial water purification systems)、and (3) MITC (as an antimicrobial agent to treat wood poles and pilings) are eligible for reregistration、provided the risk mitigation measures outlined in、the R.E.D.、are adopted、label amendments are made to reflect these measures ...、and data are developed to assess intermediate- and long-term risk to bystanders.、Metham-sodium was introduced by Stauffer Chemical Company & later by EI du Pont de Nemours & Company、Inc、& ICI Plant Protection Division (neither of whom now market it). US patents 2、766、554、2、791、605、GBP、British patent、789、690 all Stauffer Chemical Company as code number N-869 (Stauffer)、trade marks Vapam (Stauffer)、VPM (formerly du Pont)、Sistan (ICI).、...、Metham sodium gives、a complete kill of root knot nematodes in sandy soil at 5 ppm. It is an effective non-selective herbicide at rates of ... 200 lb、acre. ... it is particularly effective in cracks & under walks where the methyl isothiocyanate is confined.、For more General Manufacturing Information (Complete) data for SODIUM METHYLDITHIOCARBAMATE (11 total)。
Metham-Sodium 是一种无机化合物，登记 CAS 号为 137-42-8，分子式 C2H4NNaS2（分子量 129.18），归属于无机化学品大类化工原料。
登记 CAS 号：137-42-8
其分子式 C2H4NNaS2 由 2 个碳、4 个氢、1 个氮、1 个钠、2 个硫 组成。
别名/同义词：Metham-Sodium · metam-sodium
所属分类：无机化学品
Metham-Sodium 的 CAS 登记号为 137-42-8。
分子式 C2H4NNaS2，分子量 129.18。
别名/同义词：Metham-Sodium、metam-sodium。
登记用途：Uses: Used as a fungicide and nematicide、[Kanerva、p. 1834] Used as a soil fumigant for control of weeds、weed seeds、nematodes、fungi、and soil insects、[Merck Index] Used as non-selective soil fumigant that possesses fungicidal、herbicidal、insecticidal、and nematicidal properties、Approved for use on food、feed、and fiber crops、turf grass、sewers、and drained ponds and lakes (California only)、Also used as antimicrobial agent for wood poles、leather processing、sugar cane and beet processing、sewage sludge、and animal waste、[Reference #2] Approved for use in the EU as a pre-plant soil disinfectant for vegetables、fruit trees、grape vines、nurseries、ornamentals、and other crops、[EFSA]、Restricted use pesticide for application on golf courses、small areas of turf and soil、and in sewers and drains、[Reference #2]、Applying Wood Preservatives [Category: Other]、Farming (Pesticides) [Category: Industry]、Sewer and Wastewater Treatment [Category: Industry]、Leather Tanning and Processing [Category: Industry]、For Sodium Methyldithiocarbamate (USEPA、OPP Pesticide Code: 039003) ACTIVE products with label matches.、SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal、state and local authorities must be consulted for currently approved uses.、Metam-sodium and metam-potassium are broad spectrum fumigants with fungicidal、bactericidal、algaecide、nematicidal、and antimicrobial properties. They are dithiocarbamate salts that break down quickly in the environment to the primary toxic degradate、methyl isothiocyanate (MITC). MITC is highly volatile and is responsible for the fumigant properties of metam-sodium and metam-potassium.、Restricted Use Pesticide (RUP) Classification. MITC、the byproduct of metam sodium、metam potassium、and dazomet、meets the criteria for restricted use based on human hazard criteria and exposure incidents. All soil fumigant products containing metam sodium or metam potassium will be RUPs.、Soil fumigant to control weeds and weed seeds、amd soil insects、For more Uses (Complete) data for SODIUM METHYLDITHIOCARBAMATE (11 total)、please visit the HSDB record page.、Use Classification: SOIL FUNGICIDES、Methods of Manufacturing:、It is、prepared from methylamine、carbon disulfide and sodium hydroxide、From methyl isothiocyanate and sodium bisulfide.、Metam sodium is produced by reaction of methylamine with carbon disulfide and sodium hydroxide.、Formulations、Preparations: Soluble concentrates、aqueous solutions.、... Since、pure metham、is unstable、the commercial formulation (Vapam) is always kept as a concentrated 32.7% solution in water.、Trade Names ... Metam 426、Polefume、Turfcure、Vapam、Vapam HL、Busan 1236、Nemasol、Metam CLR、Sectagon 42、Sistan、Meter、Soldier、Basamid liquid (aq formulation containing 45% methylcarbamodithionic acid monosodium salt as ai)、Metam-Fluid (aq formulation containing 42.2% methylcarbamodithionic acid monosodium salt as ai)、VAPAM technical (technical formulation containing 32.9% methylcarbamodithionic acid monosodium salt as ai)、For more Formulations、Preparations (Complete) data for SODIUM METHYLDITHIOCARBAMATE (37 total)、Consumption Patterns: Approximately 51-55 million pounds of metam-sodium and 1-2 million pounds of metam-potassium used in the U.S. in 2002.、U.S. Production: Carbamodithioic acid、methyl-、monosodium salt is listed as a High Production Volume (HPV) chemical (65FR81686). Chemicals listed as HPV were produced in or imported into the U.S. in >1 million pounds in 1990 and、or 1994. The HPV list is based on the 1990 Inventory Update Rule. (IUR) (40 CFR part 710 subpart B、51FR21438).、General Manufacturing Information: The WHO Recommended Classification of Pesticides by Hazard identifies Metam-sodium (technical grade) as Class II: moderately hazardous、Main Use: fungicide-applied to soil: not used with herbicides or plant growth regulators.、The、USEPA、has determined that certain uses of (1) metam sodium (including use as a pre-plant soil fumigant in certain crops、specified、in the R.E.D.、and as a root control agent in sewers and drains、and as an antimicrobial agent to treat wood poles and timbers and sewage sludge and animal waste)、(2) metam-potassium (including as a pre-plant soil fumigant in certain crops、specified later in this document、and as an antimicrobial agent for treatment of pulp and paper、tanning drum leather applications、recirculating cooling water systems、and industrial water purification systems)、and (3) MITC (as an antimicrobial agent to treat wood poles and pilings) are eligible for reregistration、provided the risk mitigation measures outlined in、the R.E.D.、are adopted、label amendments are made to reflect these measures ...、and data are developed to assess intermediate- and long-term risk to bystanders.、Metham-sodium was introduced by Stauffer Chemical Company & later by EI du Pont de Nemours & Company、Inc、& ICI Plant Protection Division (neither of whom now market it). US patents 2、766、554、2、791、605、GBP、British patent、789、690 all Stauffer Chemical Company as code number N-869 (Stauffer)、trade marks Vapam (Stauffer)、VPM (formerly du Pont)、Sistan (ICI).、...、Metham sodium gives、a complete kill of root knot nematodes in sandy soil at 5 ppm. It is an effective non-selective herbicide at rates of ... 200 lb、acre. ... it is particularly effective in cracks & under walks where the methyl isothiocyanate is confined.、For more General Manufacturing Information (Complete) data for SODIUM METHYLDITHIOCARBAMATE (11 total)。
所属分类：Inorganic Chemicals。
Metham-Sodium（CAS 137-42-8）的独立参考数据，整理自公开化学数据库。
| CAS Registry Number | 137-42-8 |
|---|---|
| PubChem CID | 5366415 |
| Molecular formula | C2H4NNaS2 |
| IUPAC name | sodium N-methylcarbamodithioate |
| UNII (FDA) | 3CD7UKN224 |
| Molecular Weight | 129.18 |
|---|---|
| Hydrogen Bond Donor Count | 1 |
| Hydrogen Bond Acceptor Count | 2 |
| Rotatable Bond Count | 0 |
| Exact Mass | 128.96828576 |
| Monoisotopic Mass | 128.96828576 |
| Topological Polar Surface Area | 45.1 |
| Heavy Atom Count | 6 |
| Solubility | In water, 7.22X10+5 mg/L at 20 °C |
|---|---|
| LogP | log Kow <1 at 25 °C |
Metam-sodium; Metam sodium; Carbathione; Carbothion; Metamsodium; Trimaton; SMDC; Carbation; Karbation; Masposol; Mapasol; Sepivam; Sistan; Sometam; Carbam; Geort
| Reported hazard statements | H302, H314, H317, H400, H410, H311 (75.8%), H319 (55.9%), H332 (19.9%) |
|---|
H302: Harmful if swallowed [Warning Acute toxicity, oral]
H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
Metham-Sodium · CAS 137-42-8 · C2H4NNaS2. UNII 3CD7UKN224. Solubility: In water, 7.22X10+5 mg/L at 20 °C; LogP: log Kow <1 at 25 °C.
数据来源：PubChem / Wikidata；与随货 COA 不一致时以 COA 为准。
English page: Metham-Sodium