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Glycidyl methacrylate

CAS 106-91-2C7H10O3MW 142.06 g/mol

Glycidyl methacrylate (CAS 106-91-2) — formula C7H10O3, molecular weight 142.06 g/mol.

Product Overview

CAS Number106-91-2
Molecular FormulaC7H10O3
Molecular Weight142.06 g/mol
Melting Pointfreezing pt: -41.5 °C
Boiling Point372 °F at 760 mmHg (NTP, 1992)
LogP0.96
ApplicationsUses: Chemical intermediate for polymers, monomer and diluent in epoxy resin formulations, [HSDB] Used in Japan as an intermediate for resins and other chemicals, Also used in emulsions for impregnating paper and textiles, in paint coatings, and adhesive applications, [OECD SIDS: Glycidyl methacrylate - 1999], Pulp and Paper Processing [Category: Industry], Painting (Pigments, Binders, and Biocides) [Category: Paint], Working with Glues and Adhesives [Category: Other], Textiles (Printing, Dyeing, or Finishing) [Category: Industry], CHEM INT FOR POLYMERS, MONOMER & DILUENT IN EPOXY RESIN FORMULATIONS., In hydrogel lenses., In BIS-GMA dental resin., Adhesion promotion, crosslinking comonomer (acrylic, vinyl resins), Industry Uses: Filler, Not Known or Reasonably Ascertainable, Surface modifier, Other, Monomers, Methods of Manufacturing: REACTION OF METHACRYLIC ACID WITH GLYCIDOL, The methacrylates can be synthesized by catalytic oxidation of isobutylene and subsequent esterification with the appropriate alcohol, or by reacting acetone with hydrocyanic acid and subsequent esterification in sulfuric acid with the appropriate alcohol., Methacrylic esters, Epichlorohydrin + methacrylic acid (esterification), Formulations, Preparations: Grades or purity: Technical: 92%, Inhibitor of polymerization: Hydroquinone monomethyl ether: 50 ppm, U.S. Production: 2023: 10, 000, 000 - <50, 000 lb, 2022: 1, 000 - <5, 2021: 10, 2020: 10, (1972) GREATER THAN 4.54X10+5 G, (1975) GREATER THAN 4.54X10+5 G, U.S. Imports: (1983) 1.36X10+9 g, Acrylates & Acrylic Acid, General Manufacturing Information: Plastics Material and Resin Manufacturing, Paint and Coating Manufacturing, All Other Chemical Product and Preparation Manufacturing, Asphalt Paving, Roofing, and Coating Materials Manufacturing, 2-Propenoic acid, 2-methyl-, 2-oxiranylmethyl ester: ACTIVE, METHYL METHACRYLATE, AND IN GENERAL THE METHACRYLIC ESTERS, POLYMERIZE MUCH LESS READILY THAN THE CORRESPONDING ORDINARY ACRYLATES. NONE THE LESS, THEY ARE STABILIZED BY ADDING HYDROQUINONE OR PYROGALLOL, PARTICULARLY IN THE PRESENCE OF METALLIC COPPER., METHACRYLATES

Applications

Documented applications: Uses: Chemical intermediate for polymers, monomer and diluent in epoxy resin formulations, [HSDB] Used in Japan as an intermediate for resins and other chemicals, Also used in emulsions for impregnating paper and textiles, in paint coatings, and adhesive applications, [OECD SIDS: Glycidyl methacrylate - 1999], Pulp and Paper Processing [Category: Industry], Painting (Pigments, Binders, and Biocides) [Category: Paint], Working with Glues and Adhesives [Category: Other], Textiles (Printing, Dyeing, or Finishing) [Category: Industry], CHEM INT FOR POLYMERS, MONOMER & DILUENT IN EPOXY RESIN FORMULATIONS., In hydrogel lenses., In BIS-GMA dental resin., Adhesion promotion, crosslinking comonomer (acrylic, vinyl resins), Industry Uses: Filler, Not Known or Reasonably Ascertainable, Surface modifier, Other, Monomers, Methods of Manufacturing: REACTION OF METHACRYLIC ACID WITH GLYCIDOL, The methacrylates can be synthesized by catalytic oxidation of isobutylene and subsequent esterification with the appropriate alcohol, or by reacting acetone with hydrocyanic acid and subsequent esterification in sulfuric acid with the appropriate alcohol., Methacrylic esters, Epichlorohydrin + methacrylic acid (esterification), Formulations, Preparations: Grades or purity: Technical: 92%, Inhibitor of polymerization: Hydroquinone monomethyl ether: 50 ppm, U.S. Production: 2023: 10, 000, 000 - <50, 000 lb, 2022: 1, 000 - <5, 2021: 10, 2020: 10, (1972) GREATER THAN 4.54X10+5 G, (1975) GREATER THAN 4.54X10+5 G, U.S. Imports: (1983) 1.36X10+9 g, Acrylates & Acrylic Acid, General Manufacturing Information: Plastics Material and Resin Manufacturing, Paint and Coating Manufacturing, All Other Chemical Product and Preparation Manufacturing, Asphalt Paving, Roofing, and Coating Materials Manufacturing, 2-Propenoic acid, 2-methyl-, 2-oxiranylmethyl ester: ACTIVE, METHYL METHACRYLATE, AND IN GENERAL THE METHACRYLIC ESTERS, POLYMERIZE MUCH LESS READILY THAN THE CORRESPONDING ORDINARY ACRYLATES. NONE THE LESS, THEY ARE STABILIZED BY ADDING HYDROQUINONE OR PYROGALLOL, PARTICULARLY IN THE PRESENCE OF METALLIC COPPER., METHACRYLATES.

Technical Profile

What this product is

Glycidyl methacrylate is a chemical compound with CAS registry number 106-91-2 and molecular formula C7H10O3 (molecular weight 142.06 g/mol).

Identification

CAS number: 106-91-2

Its molecular formula C7H10O3 comprises 7 C, 10 H, 3 O atoms.

Also known as: Glycidyl methacrylate · 甲基丙烯酸缩水甘油酯

Frequently Asked Questions

What is the CAS number of Glycidyl methacrylate?

The CAS registry number of Glycidyl methacrylate is 106-91-2.

What is the molecular formula and molecular weight of Glycidyl methacrylate?

Molecular formula C7H10O3, molecular weight 142.06 g/mol.

What other names is Glycidyl methacrylate known by?

It is also registered under: Glycidyl methacrylate, 甲基丙烯酸缩水甘油酯.

What are the documented applications of Glycidyl methacrylate?

Recorded applications: Uses: Chemical intermediate for polymers, monomer and diluent in epoxy resin formulations, [HSDB] Used in Japan as an intermediate for resins and other chemicals, Also used in emulsions for impregnating paper and textiles, in paint coatings, and adhesive applications, [OECD SIDS: Glycidyl methacrylate - 1999], Pulp and Paper Processing [Category: Industry], Painting (Pigments, Binders, and Biocides) [Category: Paint], Working with Glues and Adhesives [Category: Other], Textiles (Printing, Dyeing, or Finishing) [Category: Industry], CHEM INT FOR POLYMERS, MONOMER & DILUENT IN EPOXY RESIN FORMULATIONS., In hydrogel lenses., In BIS-GMA dental resin., Adhesion promotion, crosslinking comonomer (acrylic, vinyl resins), Industry Uses: Filler, Not Known or Reasonably Ascertainable, Surface modifier, Other, Monomers, Methods of Manufacturing: REACTION OF METHACRYLIC ACID WITH GLYCIDOL, The methacrylates can be synthesized by catalytic oxidation of isobutylene and subsequent esterification with the appropriate alcohol, or by reacting acetone with hydrocyanic acid and subsequent esterification in sulfuric acid with the appropriate alcohol., Methacrylic esters, Epichlorohydrin + methacrylic acid (esterification), Formulations, Preparations: Grades or purity: Technical: 92%, Inhibitor of polymerization: Hydroquinone monomethyl ether: 50 ppm, U.S. Production: 2023: 10, 000, 000 - <50, 000 lb, 2022: 1, 000 - <5, 2021: 10, 2020: 10, (1972) GREATER THAN 4.54X10+5 G, (1975) GREATER THAN 4.54X10+5 G, U.S. Imports: (1983) 1.36X10+9 g, Acrylates & Acrylic Acid, General Manufacturing Information: Plastics Material and Resin Manufacturing, Paint and Coating Manufacturing, All Other Chemical Product and Preparation Manufacturing, Asphalt Paving, Roofing, and Coating Materials Manufacturing, 2-Propenoic acid, 2-methyl-, 2-oxiranylmethyl ester: ACTIVE, METHYL METHACRYLATE, AND IN GENERAL THE METHACRYLIC ESTERS, POLYMERIZE MUCH LESS READILY THAN THE CORRESPONDING ORDINARY ACRYLATES. NONE THE LESS, THEY ARE STABILIZED BY ADDING HYDROQUINONE OR PYROGALLOL, PARTICULARLY IN THE PRESENCE OF METALLIC COPPER., METHACRYLATES.

PubChem Public Data

Independent reference data for Glycidyl methacrylate (CAS 106-91-2), compiled from public chemistry databases.

Registry identifiers across databases

CAS Registry Number106-91-2
PubChem CID7837
Molecular formulaC7H10O3
Molecular weight142.06 g/mol
IUPAC nameoxiran-2-ylmethyl 2-methylprop-2-enoate
InChIKeyVOZRXNHHFUQHIL-UHFFFAOYSA-N
UNII (FDA)R8WN29J8VF
ChEBI IDCHEBI:132844

Computed descriptors

Molecular Weight142.15
XLogP30.8
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count3
Rotatable Bond Count4
Exact Mass142.062994177
Monoisotopic Mass142.062994177
Topological Polar Surface Area38.8
Heavy Atom Count10

Physicochemical values on record

Boiling Point372 °F at 760 mmHg (NTP, 1992)
Boiling Point189 °C
Melting Pointfreezing pt: -41.5 °C
Flash Point181 °F (NTP, 1992)
Flash Point84 °C (Tag open cup)
Solubility5 to 10 mg/mL at 68 °F (NTP, 1992)
Density1.07 g/cu cm @ 25 °C
Vapor Pressure3.15 [mmHg]
LogP0.96
Viscosity5.481 cP at 70 °F

Documented uses on record

    Chemical intermediate for polymers; monomer and diluent in epoxy resin formulations; [HSDB] Used in Japan as an intermediate for resins and other chemicals; Also used in emulsions for impregnating paper and textiles, in paint coatings, and adhesive applications; [OECD SIDS: Glycidyl methacrylate - 1999]Pulp and Paper Processing [Category: Industry]

    Synonyms and trade names

    GLYCIDYL METHACRYLATE; 106-91-2; 2,3-Epoxypropyl methacrylate; Glycidol methacrylate; SY-Monomer G; Blemmer G; Acriester G; Blemmer GMA; Light Ester G; Methacrylic acid, 2,3-epoxypropyl ester; 2-((Methacryloxy)methyl)oxirane; DTXSID0025361; 2-Propenoic acid, 2-methyl-, oxiranylmethyl ester; Glycidyl alpha-methylacrylate; CP 105; Glycidyl alpha-methyl acrylate

    Regulatory listings held on file

    Regulatory & Food ContactFDA Inventory of Food Contact Substances Listed in 21 CFR: FCS
    FDA Inventory of Effective Food Contact Substance (FCS) Noti: FCS
    Glycidyl methacrylate (CAS Reg. No. 106-91-2)
    As a monomer in the manufacture of acrylic copolymers complying with 21 CFR 175.300 (b)(3)(xx) for use as comp
    GHS notification summary0.1% (1 / 1165)

    GHS hazard classification

    GHS notification summary0.1% (1 / 1165)
    Reported hazard statementsH302, H311, H314, H317, H318, H335, H341, H350

    H302: Harmful if swallowed [Warning Acute toxicity, oral]

    H311: Toxic in contact with skin [Danger Acute toxicity, dermal]

    What the public record says

    Glycidyl methacrylate is identified by CAS 106-91-2, molecular formula C7H10O3 and molecular weight 142.06 g/mol. UNII R8WN29J8VF; ChEBI 132844; InChIKey VOZRXNHHFUQHIL-UHFFFAOYSA-N. Boiling Point: 372 °F at 760 mmHg (NTP, 1992); Boiling Point: 189 °C; Melting Point: freezing pt: -41.5 °C.

    Physical description and handling notes

    Source: PubChem / Wikidata; the batch COA governs where values differ.

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