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Diisobutylaluminum hydride

CAS 1191-15-7C8H19AlMW 142.22

Diisobutylaluminum hydride (CAS 1191-15-7) — formula C8H19Al, molecular weight 142.22; category inorganic chemicals.

Product Overview

CAS Number1191-15-7
Molecular FormulaC8H19Al
Molecular Weight142.22
Melting Point-80 °C (Freezing point)
Boiling Point105 °C @ 0.2 mm Hg
ApplicationsUses: Used as a reducing agent (pharmaceuticals, aldehydes, amides, and olefins), a polymerization catalyst for polyethylene, and an intermediate in silicones, certain polymers, and organic acid synthesis, [HSDB] Organic aluminum compounds are some of the most important, highest volume, highest value organometallic compounds in production. [Ullmann], ... Reduction of the aldehyde or ketone carbonyl function to an alcohol., Reducing agent in pharmaceuticals, REDUCING AGENT, EG, FOR ALDEHYDES, AMIDES & OLEFINS, POLYMERIZATION CATALYST FOR POLYETHYLENE, ...Intermediates in silicones, certain polymers and organic acid synthesis., Diisobutylaluminium hydride is a reducing agent used in organic synthesis. (L774), Industry Uses: Not Known or Reasonably Ascertainable, Methods of Manufacturing: Reaction of isobutylene and hydrogen with aluminum., CONTROLLED THERMAL DECOMPOSITION OF TRIISOBUTYLALUMINUM TO DIISOBUTYLALUMINUM HYDRIDE & ISOBUTENE, DIRECT REACTION OF ALUMINUM, HYDROGEN, & TRIISOBUTYLALUMINUM, Formulations, Preparations: SUPPLIED AS A SOLN IN HYDROCARBON SOLVENTS., U.S. Production: 2023: 1, 000, 000 - <2, 500, 000 lb, 2022: 1, 2021: 1, 2020: 850, 000 - <1, (1979) PROBABLY GREATER THAN 4.54X10+6 GRAMS, General Manufacturing Information: Not Known or Reasonably Ascertainable, Aluminum, hydrobis(2-methylpropyl)-: ACTIVE
CategoryInorganic Chemicals

Applications

Documented applications: Uses: Used as a reducing agent (pharmaceuticals, aldehydes, amides, and olefins), a polymerization catalyst for polyethylene, and an intermediate in silicones, certain polymers, and organic acid synthesis, [HSDB] Organic aluminum compounds are some of the most important, highest volume, highest value organometallic compounds in production. [Ullmann], ... Reduction of the aldehyde or ketone carbonyl function to an alcohol., Reducing agent in pharmaceuticals, REDUCING AGENT, EG, FOR ALDEHYDES, AMIDES & OLEFINS, POLYMERIZATION CATALYST FOR POLYETHYLENE, ...Intermediates in silicones, certain polymers and organic acid synthesis., Diisobutylaluminium hydride is a reducing agent used in organic synthesis. (L774), Industry Uses: Not Known or Reasonably Ascertainable, Methods of Manufacturing: Reaction of isobutylene and hydrogen with aluminum., CONTROLLED THERMAL DECOMPOSITION OF TRIISOBUTYLALUMINUM TO DIISOBUTYLALUMINUM HYDRIDE & ISOBUTENE, DIRECT REACTION OF ALUMINUM, HYDROGEN, & TRIISOBUTYLALUMINUM, Formulations, Preparations: SUPPLIED AS A SOLN IN HYDROCARBON SOLVENTS., U.S. Production: 2023: 1, 000, 000 - <2, 500, 000 lb, 2022: 1, 2021: 1, 2020: 850, 000 - <1, (1979) PROBABLY GREATER THAN 4.54X10+6 GRAMS, General Manufacturing Information: Not Known or Reasonably Ascertainable, Aluminum, hydrobis(2-methylpropyl)-: ACTIVE.

Technical Profile

What this product is

Diisobutylaluminum hydride is an inorganic compound with CAS registry number 1191-15-7 and molecular formula C8H19Al (molecular weight 142.22), belonging to the inorganic chemicals segment of chemical raw materials.

Identification

CAS number: 1191-15-7

Its molecular formula C8H19Al comprises 8 C, 19 H, 1 Al atoms.

Also known as: Diisobutylaluminum hydride · 二异丁基氢化铝

Category: inorganic chemicals

Frequently Asked Questions

What is the CAS number of Diisobutylaluminum hydride?

The CAS registry number of Diisobutylaluminum hydride is 1191-15-7.

What is the molecular formula and molecular weight of Diisobutylaluminum hydride?

Molecular formula C8H19Al, molecular weight 142.22.

What other names is Diisobutylaluminum hydride known by?

It is also registered under: Diisobutylaluminum hydride, 二异丁基氢化铝.

What are the documented applications of Diisobutylaluminum hydride?

Recorded applications: Uses: Used as a reducing agent (pharmaceuticals, aldehydes, amides, and olefins), a polymerization catalyst for polyethylene, and an intermediate in silicones, certain polymers, and organic acid synthesis, [HSDB] Organic aluminum compounds are some of the most important, highest volume, highest value organometallic compounds in production. [Ullmann], ... Reduction of the aldehyde or ketone carbonyl function to an alcohol., Reducing agent in pharmaceuticals, REDUCING AGENT, EG, FOR ALDEHYDES, AMIDES & OLEFINS, POLYMERIZATION CATALYST FOR POLYETHYLENE, ...Intermediates in silicones, certain polymers and organic acid synthesis., Diisobutylaluminium hydride is a reducing agent used in organic synthesis. (L774), Industry Uses: Not Known or Reasonably Ascertainable, Methods of Manufacturing: Reaction of isobutylene and hydrogen with aluminum., CONTROLLED THERMAL DECOMPOSITION OF TRIISOBUTYLALUMINUM TO DIISOBUTYLALUMINUM HYDRIDE & ISOBUTENE, DIRECT REACTION OF ALUMINUM, HYDROGEN, & TRIISOBUTYLALUMINUM, Formulations, Preparations: SUPPLIED AS A SOLN IN HYDROCARBON SOLVENTS., U.S. Production: 2023: 1, 000, 000 - <2, 500, 000 lb, 2022: 1, 2021: 1, 2020: 850, 000 - <1, (1979) PROBABLY GREATER THAN 4.54X10+6 GRAMS, General Manufacturing Information: Not Known or Reasonably Ascertainable, Aluminum, hydrobis(2-methylpropyl)-: ACTIVE.

Which category does Diisobutylaluminum hydride belong to?

Category: Inorganic Chemicals.

PubChem Public Data

Independent reference data for Diisobutylaluminum hydride (CAS 1191-15-7), compiled from public chemistry databases.

Registry identifiers across databases

CAS Registry Number1191-15-7
PubChem CID14487
Molecular formulaC8H19Al
IUPAC namebis(2-methylpropyl)alumane
UNII (FDA)H2EJ47H11A

Computed descriptors

Molecular Weight142.22
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count0
Rotatable Bond Count4
Exact Mass142.1302140
Monoisotopic Mass142.1302140
Topological Polar Surface Area0
Heavy Atom Count9

Physicochemical values on record

Boiling Point105 °C @ 0.2 mm Hg
Melting Point-80 °C (Freezing point)
Melting Point-80 °C
Density0.798 g/mL
Density0.798 @25 °C

Documented uses on record

    Used as a reducing agent (pharmaceuticals, aldehydes, amides, and olefins), a polymerization catalyst for polyethylene, and an intermediate in silicones, certain polymers, and organic acid synthesis; [HSDB] Organic aluminum compounds are some of the most important, highest volume, highest value organometallic compounds in production. [Ullmann]... Reduction of the aldehyde or ketone carbonyl function to an alcohol.

    Synonyms and trade names

    Dibal-H; bis(2-methylpropyl)alumane; Diisobutylhydroaluminum; Al-Diisobutyl; Al-Alchili; Diisobutylaluminum; Hydrodiisobutylaluminum; Bis(isobutyl)hydroaluminum; Aluminum, diisobutylhydro-; Aluminum, hydrodiisobutyl-; H2EJ47H11A; DTXSID4041866; Hydrobis(2-methylpropyl)aluminum; DIBALH cpd; RefChem:134038; DTXCID2021866

    GHS hazard classification

    Reported hazard statementsH250 (97.7%), H260 (93.1%), H314 (100%), H318 (83.2%)

    H250 (97.7%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]

    H260 (93.1%): In contact with water releases flammable gases which may ignite spontaneously [Danger Substances and mixtures which in contact with water, emit flammable gases]

    What the public record says

    Diisobutylaluminum hydride · CAS 1191-15-7 · C8H19Al. UNII H2EJ47H11A. Boiling Point: 105 °C @ 0.2 mm Hg; Melting Point: -80 °C (Freezing point); Melting Point: -80 °C.

    Physical description and handling notes

    Source: PubChem / Wikidata; the batch COA governs where values differ.

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