一水氢氧化铯(CAS 35103-79-8):分子式 CsHO、分子量 149.913。
| CAS号 | 35103-79-8 |
|---|---|
| 分子式 | CsHO |
| 分子量 | 149.913 |
| 熔点 | 522 °F (NIOSH, 2024) |
| 应用领域 | Uses: Used as a polymerization catalyst、also used in photography and in electrolyte solutions for storage batteries、[HSDB]、Battery Manufacturing [Category: Industry]、Photographic Processing [Category: Other]、Polyols are important raw materials for the production of polyurethane foams. Their synthesis profits from use of cesium hydroxide as base catalyst. In polyol synthesis isomerization of the starting material propylene oxide is an adverse side reaction eventually leading to chain termination in the polymerization with polyisocyanate. The tendency of polyols to undergo isomerization is minimized when using cesium hydroxide、as isomerization tendency decreases in the order Li > Na > K > Rb > Cs.、Recommended as electrolyte in alkaline storage batteries at subzero temperatures、polymerization catalyst for siloxanes.、Industry Uses: Intermediate、Methods of Manufacturing: Alkaline decomposition can be carried out either by mixing、powdered pollucite、ore with lime and calcium chloride and heating to 800 - 900 °C followed by leaching of the residue or by heating pollucite with sodium chloride and soda ash to 600 - 800 °C followed by leaching. Both processes furnish impure solutions of cesium chloride. Hydrothermal alkaline leaching with Ca(OH)2 at 200 - 280 °C under high pressure has been developed as an industrial process to yield a low-purity cesium hydroxide directly from pollucite.、By adding barium hydroxide to an aqueous solution of cesium sulfate.、Formulations、Preparations: Prepared by electrolysis of Cs salts、Grade: Technical、50% aqueous solution.、U.S. Production: 2023: <50、000 lb、2022: <50、2021: <50、2020: 50、000 - <250、General Manufacturing Information: All Other Basic Inorganic Chemical Manufacturing、Cesium hydroxide (Cs(OH)): ACTIVE、If cesium is exposed to air、explosion-like oxidation to form cesium superoxide ... occurs、contact with water results in a vigourous reaction to form cesium hydroxide and hydrogen gas、which may ignite spontaneously |
登记用途:Uses: Used as a polymerization catalyst、also used in photography and in electrolyte solutions for storage batteries、[HSDB]、Battery Manufacturing [Category: Industry]、Photographic Processing [Category: Other]、Polyols are important raw materials for the production of polyurethane foams. Their synthesis profits from use of cesium hydroxide as base catalyst. In polyol synthesis isomerization of the starting material propylene oxide is an adverse side reaction eventually leading to chain termination in the polymerization with polyisocyanate. The tendency of polyols to undergo isomerization is minimized when using cesium hydroxide、as isomerization tendency decreases in the order Li > Na > K > Rb > Cs.、Recommended as electrolyte in alkaline storage batteries at subzero temperatures、polymerization catalyst for siloxanes.、Industry Uses: Intermediate、Methods of Manufacturing: Alkaline decomposition can be carried out either by mixing、powdered pollucite、ore with lime and calcium chloride and heating to 800 - 900 °C followed by leaching of the residue or by heating pollucite with sodium chloride and soda ash to 600 - 800 °C followed by leaching. Both processes furnish impure solutions of cesium chloride. Hydrothermal alkaline leaching with Ca(OH)2 at 200 - 280 °C under high pressure has been developed as an industrial process to yield a low-purity cesium hydroxide directly from pollucite.、By adding barium hydroxide to an aqueous solution of cesium sulfate.、Formulations、Preparations: Prepared by electrolysis of Cs salts、Grade: Technical、50% aqueous solution.、U.S. Production: 2023: <50、000 lb、2022: <50、2021: <50、2020: 50、000 - <250、General Manufacturing Information: All Other Basic Inorganic Chemical Manufacturing、Cesium hydroxide (Cs(OH)): ACTIVE、If cesium is exposed to air、explosion-like oxidation to form cesium superoxide ... occurs、contact with water results in a vigourous reaction to form cesium hydroxide and hydrogen gas、which may ignite spontaneously。
一水氢氧化铯 是一种化工化合物,登记 CAS 号为 35103-79-8,分子式 CsHO(分子量 149.913)。
登记 CAS 号:35103-79-8
其分子式 CsHO 由 1 个铯、1 个氢、1 个氧 组成。
别名/同义词:一水氢氧化铯 · Cesium hydroxide monohydrate
一水氢氧化铯 的 CAS 登记号为 35103-79-8。
分子式 CsHO,分子量 149.913。
别名/同义词:一水氢氧化铯、Cesium hydroxide monohydrate。
登记用途:Uses: Used as a polymerization catalyst、also used in photography and in electrolyte solutions for storage batteries、[HSDB]、Battery Manufacturing [Category: Industry]、Photographic Processing [Category: Other]、Polyols are important raw materials for the production of polyurethane foams. Their synthesis profits from use of cesium hydroxide as base catalyst. In polyol synthesis isomerization of the starting material propylene oxide is an adverse side reaction eventually leading to chain termination in the polymerization with polyisocyanate. The tendency of polyols to undergo isomerization is minimized when using cesium hydroxide、as isomerization tendency decreases in the order Li > Na > K > Rb > Cs.、Recommended as electrolyte in alkaline storage batteries at subzero temperatures、polymerization catalyst for siloxanes.、Industry Uses: Intermediate、Methods of Manufacturing: Alkaline decomposition can be carried out either by mixing、powdered pollucite、ore with lime and calcium chloride and heating to 800 - 900 °C followed by leaching of the residue or by heating pollucite with sodium chloride and soda ash to 600 - 800 °C followed by leaching. Both processes furnish impure solutions of cesium chloride. Hydrothermal alkaline leaching with Ca(OH)2 at 200 - 280 °C under high pressure has been developed as an industrial process to yield a low-purity cesium hydroxide directly from pollucite.、By adding barium hydroxide to an aqueous solution of cesium sulfate.、Formulations、Preparations: Prepared by electrolysis of Cs salts、Grade: Technical、50% aqueous solution.、U.S. Production: 2023: <50、000 lb、2022: <50、2021: <50、2020: 50、000 - <250、General Manufacturing Information: All Other Basic Inorganic Chemical Manufacturing、Cesium hydroxide (Cs(OH)): ACTIVE、If cesium is exposed to air、explosion-like oxidation to form cesium superoxide ... occurs、contact with water results in a vigourous reaction to form cesium hydroxide and hydrogen gas、which may ignite spontaneously。
一水氢氧化铯(CAS 35103-79-8)的独立参考数据,整理自公开化学数据库。
| CAS Registry Number | 35103-79-8 |
|---|---|
| PubChem CID | 62750 |
| Molecular formula | CsHO |
| IUPAC name | cesium hydroxide |
| UNII (FDA) | 458ZFZ6235 |
| Molecular Weight | 149.913 |
|---|---|
| Hydrogen Bond Donor Count | 1 |
| Hydrogen Bond Acceptor Count | 1 |
| Rotatable Bond Count | 0 |
| Exact Mass | 149.90819161 |
| Monoisotopic Mass | 149.90819161 |
| Topological Polar Surface Area | 1 |
| Heavy Atom Count | 2 |
| Melting Point | 522 °F (NIOSH, 2024) |
|---|---|
| Melting Point | 342.3 °C |
| Melting Point | MP: 272.3 °C |
| Melting Point | 272 °C |
| Melting Point | 522 °F |
| Melting Point | 315 °C |
| Solubility | 395 % at 59 °F (NIOSH, 2024) |
| Solubility | 300 g/100 g water at 30 °C |
| Solubility | (59 °F): 395% |
| Density | 3.68 g/cu cm |
Cesium hydroxide; 21351-79-1; Caesium hydroxide; 12182-83-1; Cesium hydroxide (Cs(OH)); UN2681; UN2682; EINECS 244-344-1; 458ZFZ6235; NSC 121987; UNII-458ZFZ6235; HSDB 7906; NSC-121987; CESIUM HYDROXIDE [MI]; DTXSID7066699; CHEBI:33988
| Reported hazard statements | H302 (97.8%), H314 (99.6%), H318 (65.8%), H361 (19.6%), H373 (65.8%), H402, H330, H335 |
|---|
H302 (97.8%): Harmful if swallowed [Warning Acute toxicity, oral]
H314 (99.6%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
Cesium hydroxide monohydrate · CAS 35103-79-8 · CsHO. UNII 458ZFZ6235. Melting Point: 522 °F (NIOSH, 2024); Melting Point: 342.3 °C; Melting Point: MP: 272.3 °C.
数据来源:PubChem / Wikidata;与随货 COA 不一致时以 COA 为准。
English page: Cesium hydroxide monohydrate