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Cesium chloride

CAS 7647-17-8CsClMW 167.87 g/mol

Cesium chloride (CAS 7647-17-8) — formula CsCl, molecular weight 167.87 g/mol; category specialty chemicals.

Product Overview

CAS Number7647-17-8
Molecular FormulaCsCl
Molecular Weight167.87 g/mol
Melting Point646 °C
Boiling Point1290 °C (sublimes)
ApplicationsUses: Used in x-ray screens and radiographic contrast medium, [Merck Index], In x-ray fluorescent screens, as radiographic contrast medium, in manuf of cesium., There are currently 160 gamma-irradiation facilities and over 600 electron-beam facilities in operation throughout the world. The most widespread uses of these facilities are the sterilization of medical and pharmaceutical products, the preservation of foodstuffs, polymer synthesis and modification, and the eradication of insect infestation For gamma facilities the source would typically be 60Co in the petabequerel range, some 137Cs sources are also used., Both x-ray equipment and sealed sources are used in industrial radiography. The most common sealed sources are 192Ir..., 60Co..., and 137Cs (activity between 0.3 and 80 GBq)., Methods of Manufacturing: Alkaline decomposition is carried out by roasting the pollucite ore with either a calcium carbonate-calcium chloride mix at 800-900 °C or with a sodium carbonate-sodium chloride mix at 600-800 °C followed by a water leach of the roasted mass. The resultant cesium chloride solution is separated from the gangue by filtration., Acid digestion of pollucite is the preferred commercial process for producing pure cesium. Hydrofluoric, hydrobromic, and sulfuric acid may be employed in this method. Hydrofluoric and hydrobromic acid digestion yield the greatest cesium recovery, but the inherent difficulties of safely handling these acids limit their use. Digestion with hydrochloric acid takes place at elevated temperatures and produces a solution of mixed cesium chlorides, aluminum, and other alkali metals separated from the siliceous residue by filtration. The impure cesium chloride can be purified as cesium chloride double salts that are then recrystallized. The purified double salts are decomposed to cesium chloride by hydrolysis or precipitated with hydrogen sulfide., Sulfuric acid digestion is performed at 110 °C with a 35-40% solution of sulfuric acid, followed by a hot water wash and vacuum filtration. Cesium alum is crystallized from the leach filtrate by stage cooling to 50 °C and then 20 °C, and roasted in the presence of 4% carbon. The residue is leached to produce cesium sulfate solution, which can be converted to cesium chloride., General Manufacturing Information: Cesium chloride (CsCl): ACTIVE, Not produced in the USA, although there is no information regarding the countries shipping cesium compounds (e.g., cesium chloride) to the USA, it is believed that Canada is the major source of cesium compounds (e.g., cesium chloride).
CategoryNew Energy Materials

Applications

Documented applications: Uses: Used in x-ray screens and radiographic contrast medium, [Merck Index], In x-ray fluorescent screens, as radiographic contrast medium, in manuf of cesium., There are currently 160 gamma-irradiation facilities and over 600 electron-beam facilities in operation throughout the world. The most widespread uses of these facilities are the sterilization of medical and pharmaceutical products, the preservation of foodstuffs, polymer synthesis and modification, and the eradication of insect infestation For gamma facilities the source would typically be 60Co in the petabequerel range, some 137Cs sources are also used., Both x-ray equipment and sealed sources are used in industrial radiography. The most common sealed sources are 192Ir..., 60Co..., and 137Cs (activity between 0.3 and 80 GBq)., Methods of Manufacturing: Alkaline decomposition is carried out by roasting the pollucite ore with either a calcium carbonate-calcium chloride mix at 800-900 °C or with a sodium carbonate-sodium chloride mix at 600-800 °C followed by a water leach of the roasted mass. The resultant cesium chloride solution is separated from the gangue by filtration., Acid digestion of pollucite is the preferred commercial process for producing pure cesium. Hydrofluoric, hydrobromic, and sulfuric acid may be employed in this method. Hydrofluoric and hydrobromic acid digestion yield the greatest cesium recovery, but the inherent difficulties of safely handling these acids limit their use. Digestion with hydrochloric acid takes place at elevated temperatures and produces a solution of mixed cesium chlorides, aluminum, and other alkali metals separated from the siliceous residue by filtration. The impure cesium chloride can be purified as cesium chloride double salts that are then recrystallized. The purified double salts are decomposed to cesium chloride by hydrolysis or precipitated with hydrogen sulfide., Sulfuric acid digestion is performed at 110 °C with a 35-40% solution of sulfuric acid, followed by a hot water wash and vacuum filtration. Cesium alum is crystallized from the leach filtrate by stage cooling to 50 °C and then 20 °C, and roasted in the presence of 4% carbon. The residue is leached to produce cesium sulfate solution, which can be converted to cesium chloride., General Manufacturing Information: Cesium chloride (CsCl): ACTIVE, Not produced in the USA, although there is no information regarding the countries shipping cesium compounds (e.g., cesium chloride) to the USA, it is believed that Canada is the major source of cesium compounds (e.g., cesium chloride)..

Technical Profile

What this product is

Cesium chloride is a specialty compound with CAS registry number 7647-17-8 and molecular formula CsCl (molecular weight 167.87 g/mol), belonging to the specialty chemicals segment of chemical raw materials.

Identification

CAS number: 7647-17-8

Its molecular formula CsCl comprises 1 Cs, 1 Cl atoms.

Also known as: Cesium chloride

Category: specialty chemicals

Frequently Asked Questions

What is the CAS number of Cesium chloride?

The CAS registry number of Cesium chloride is 7647-17-8.

What is the molecular formula and molecular weight of Cesium chloride?

Molecular formula CsCl, molecular weight 167.87 g/mol.

What other names is Cesium chloride known by?

It is also registered under: Cesium chloride.

What are the documented applications of Cesium chloride?

Recorded applications: Uses: Used in x-ray screens and radiographic contrast medium, [Merck Index], In x-ray fluorescent screens, as radiographic contrast medium, in manuf of cesium., There are currently 160 gamma-irradiation facilities and over 600 electron-beam facilities in operation throughout the world. The most widespread uses of these facilities are the sterilization of medical and pharmaceutical products, the preservation of foodstuffs, polymer synthesis and modification, and the eradication of insect infestation For gamma facilities the source would typically be 60Co in the petabequerel range, some 137Cs sources are also used., Both x-ray equipment and sealed sources are used in industrial radiography. The most common sealed sources are 192Ir..., 60Co..., and 137Cs (activity between 0.3 and 80 GBq)., Methods of Manufacturing: Alkaline decomposition is carried out by roasting the pollucite ore with either a calcium carbonate-calcium chloride mix at 800-900 °C or with a sodium carbonate-sodium chloride mix at 600-800 °C followed by a water leach of the roasted mass. The resultant cesium chloride solution is separated from the gangue by filtration., Acid digestion of pollucite is the preferred commercial process for producing pure cesium. Hydrofluoric, hydrobromic, and sulfuric acid may be employed in this method. Hydrofluoric and hydrobromic acid digestion yield the greatest cesium recovery, but the inherent difficulties of safely handling these acids limit their use. Digestion with hydrochloric acid takes place at elevated temperatures and produces a solution of mixed cesium chlorides, aluminum, and other alkali metals separated from the siliceous residue by filtration. The impure cesium chloride can be purified as cesium chloride double salts that are then recrystallized. The purified double salts are decomposed to cesium chloride by hydrolysis or precipitated with hydrogen sulfide., Sulfuric acid digestion is performed at 110 °C with a 35-40% solution of sulfuric acid, followed by a hot water wash and vacuum filtration. Cesium alum is crystallized from the leach filtrate by stage cooling to 50 °C and then 20 °C, and roasted in the presence of 4% carbon. The residue is leached to produce cesium sulfate solution, which can be converted to cesium chloride., General Manufacturing Information: Cesium chloride (CsCl): ACTIVE, Not produced in the USA, although there is no information regarding the countries shipping cesium compounds (e.g., cesium chloride) to the USA, it is believed that Canada is the major source of cesium compounds (e.g., cesium chloride)..

Which category does Cesium chloride belong to?

Category: New Energy Materials.

PubChem Public Data

Independent reference data for Cesium chloride (CAS 7647-17-8), compiled from public chemistry databases.

Registry identifiers across databases

CAS 号7647-17-8
PubChem CID24293
分子式CsCl
分子量167.87 g/mol
IUPAC 名称cesium chloride
InChIKeyAIYUHDOJVYHVIT-UHFFFAOYSA-M
UNII(FDA)GNR9HML8BA
ChEBI 编号CHEBI:63039

Computed descriptors

Molecular Weight168.36
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count1
Rotatable Bond Count0
Exact Mass167.8743047
Monoisotopic Mass167.8743047
Topological Polar Surface Area0
Heavy Atom Count2

Physicochemical values on record

Boiling Point1290 °C (sublimes)
Boiling Point1297 °C @760 [mm Hg]
Melting Point646 °C
Density3.988
Density3.99 @25 °C

Synonyms and trade names

CESIUM CHLORIDE; 7647-17-8; Caesium chloride; Cesium monochloride; CsCl; Cesium chloride (CsCl); Tricesium trichloride; GNR9HML8BA; DTXSID3040435; NSC-15198; DTXCID1020435; CHEBI:63039; Cesium Muriaticum; Cesium Chloride 99%; RefChem:54754; 231-600-2

Regulatory listings held on file

GHS 通报统计28.4% (69 / 243)

GHS hazard classification

GHS 通报统计28.4% (69 / 243)
已通报的危害声明H361 (50.6%)

What the public record says

Cesium chloride 的 CAS 号为 7647-17-8,分子式 CsCl,分子量 167.87 g/mol。 UNII GNR9HML8BA; ChEBI 63039; InChIKey AIYUHDOJVYHVIT-UHFFFAOYSA-M. Boiling Point: 1290 °C (sublimes); Boiling Point: 1297 °C @760 [mm Hg]; Melting Point: 646 °C.

Source: PubChem / Wikidata; the batch COA governs where values differ.

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