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Biodiesel

CAS 37331-50-3H2SMW 34.08

Biodiesel (CAS 37331-50-3) — formula H2S, molecular weight 34.08.

Product Overview

CAS Number37331-50-3
Molecular FormulaH2S
Molecular Weight34.08
Melting Point-121.9 °F (EPA, 1998)
Boiling Point-76.59 °F at 760 mmHg (EPA, 1998)
LogP0.5
ApplicationsUses: Hydrogen sulfide is produced naturally by decaying organic matter and is released from sewage sludge, liquid manure, sulfur hot springs, and natural gas. It is a byproduct of many industrial processes including petroleum refining, tanning, mining, wood pulp processing, rayon manufacturing, sugar beet processing, and hot asphalt paving. Hydrogen sulfide is used to produce elemental sulfur, sulfuric acid, and heavy water for nuclear reactors. [ATSDR Medical Management], Steel Producing [Category: Industry], Petroleum Production and Refining [Category: Industry], Pulp and Paper Processing [Category: Industry], Textiles (Fiber & Fabric Manufacturing) [Category: Industry], Mining [Category: Industry], Sewer and Wastewater Treatment [Category: Industry], Leather Tanning and Processing [Category: Industry], Farming (Respiratory Hazards) [Category: Industry], Smoking cigarettes [Category: Food & Drugs], Superficial sulfurization of metals with hydrogen sulfide allows modification of their physical or chemical properties. Hydrogen sulfide is used for passivation of the walls of reactors operating at high temperature in petrochemical operations such as steam cracking and hydrodealkylation. This treatment prevents desirable secondary reactions. Another use of hydrogen sulfide is the formation of a layer of sulfide on the surface of steel wires or plates that are to be coated with paint or plastic. This treatment protects the coating or improves the action of adhesive primers., The most common industrial application of hydrogen sulfide is the production of organic compounds with a thiol function (i.e., RSH, where R is a hydrocarbon group) or a thiol group and another function (e.g., alcohol, acid)., Certain catalysts reach their maximum activity only when their constituent metals are in the form of sulfides (e.g., the hydrotreating catalysts used in oil refining). Preliminary treatment with hydrogen sulfide is sometimes necessary. However, hydrogen sulfide also poisons some hydrogenation and reforming catalysts with a platinum or palladium base. This can be used to advantage to reduce initial catalyst activity and limit coking (i.e., formation of carbonaceous deposits). Gasoline reforming catalysts, for example, are always selectively poisoned with a small quantity of hydrogen sulfide prior to use., Preliminary treatment with hydrogen sulfide is sometimes required for the purification of ore by selective flotation. ... This process is used in the purification of nickel and manganese., For more Uses (Complete) data for HYDROGEN SULFIDE (9 total), please visit the HSDB record page., Volcanoes and hot springs emit some hydrogen sulfide, where it probably arises via the hydrolysis of sulfide minerals. Hydrogen sulfide can be present naturally in well water, it can be removed using ozone or a filter with manganese dioxide. About 10% of total global emissions of H2S is due to human activity. By far the largest industrial route to hydrogen sulfide occurs in petroleum refineries. Other anthropogenic sources of hydrogen sulfide include coke ovens, paper mills, and tanneries. H2S arises from virtually anywhere where elemental sulfur comes into contact with organic material, especially at high temperatures. Being heavier than air, H2S tends to accumulate at the bottom of poorly ventilated spaces. (L1139), Use Classification: Chemical Classes -> Inorganic substances, Household Products: Information on 6 consumer products that contain Hydrogen sulfide in the following categories is provided:, • Home Maintenance, Methods of Manufacturing: Hydrogen sulfide is formed when hydrogen is fed into sulfur at 350 °C with or without a catalyst (e.g., bauxite, aluminum silicate, cobalt molybdate. High pressure also aids the reaction. ... In the industrial production of hydrogen sulfide (Fig. 1), the reaction occurs at 450 °C and 0.7 MPa. Hydrogen sulfide is separated from sulfur vapor by cooling and solidifying the sulfur on the walls of a heat exchanger. The exchanger is alternately cooled and heated to remelt and eliminate the sulfur deposit., Sulfur reacts with methane to form a mixture of hydrogen sulfide and carbon disulfide. Carbon disulfide can be hydrolyzed, giving additional hydrogen sulfide. With higher alkanes (>C10) having a low vapor pressure, reaction takes place at 200-300 °C., Hydrogen sulfide is obtained from ... gas: 1. directly if the hydrogen sulfide-carbon dioxide ratio is high enough to give an acid gas with the desired hydrogen sulfide content (80-90 vol%) or if a selective sweetening process is used, 2. after additional treatment, consisting of selective reprocessing (desired purity, 90-95%) or compression and subsequent distillation (minimum purity 99.5%)., Derivation: (1) By the action of dilute sulfuric acid on a sulfide, usually iron sulfide, (2) by direct union of hydrogen and sulfur vapor at a definite temperature and pressure, (3) as a by-product of petroleum refining., Natural gas, synthesis gas, refinery gas, coke oven gas (solvent extraction), hydrogen + sulfur (reaction), natural gas (Lacquer distillation process), natural gas + sulfur (reaction, by-product of carbon disulfide production), metallurgic coke + sulfur (reaction, coproduced with carbon disulfide)., Formulations, Preparations: Grade: Technical 98.5%, purified 99.5% min, CP, chemically pure, ., Consumption Patterns: 8.85X10+11 G AS AN INT FOR SULFURIC ACID (1966), U.S. Production: Production volumes for non-confidential chemicals reported under the Inventory Update Rule.[Table#1666], Production volume for non-confidential chemicals reported under the 2006 Inventory Update Rule. Chemical: Hydrogen sulfide. Aggregated National Production Volume: 1 billion lbs and greater., General Manufacturing Information: Hydrogen sulfide (H2S): ACTIVE

Applications

Documented applications: Uses: Hydrogen sulfide is produced naturally by decaying organic matter and is released from sewage sludge, liquid manure, sulfur hot springs, and natural gas. It is a byproduct of many industrial processes including petroleum refining, tanning, mining, wood pulp processing, rayon manufacturing, sugar beet processing, and hot asphalt paving. Hydrogen sulfide is used to produce elemental sulfur, sulfuric acid, and heavy water for nuclear reactors. [ATSDR Medical Management], Steel Producing [Category: Industry], Petroleum Production and Refining [Category: Industry], Pulp and Paper Processing [Category: Industry], Textiles (Fiber & Fabric Manufacturing) [Category: Industry], Mining [Category: Industry], Sewer and Wastewater Treatment [Category: Industry], Leather Tanning and Processing [Category: Industry], Farming (Respiratory Hazards) [Category: Industry], Smoking cigarettes [Category: Food & Drugs], Superficial sulfurization of metals with hydrogen sulfide allows modification of their physical or chemical properties. Hydrogen sulfide is used for passivation of the walls of reactors operating at high temperature in petrochemical operations such as steam cracking and hydrodealkylation. This treatment prevents desirable secondary reactions. Another use of hydrogen sulfide is the formation of a layer of sulfide on the surface of steel wires or plates that are to be coated with paint or plastic. This treatment protects the coating or improves the action of adhesive primers., The most common industrial application of hydrogen sulfide is the production of organic compounds with a thiol function (i.e., RSH, where R is a hydrocarbon group) or a thiol group and another function (e.g., alcohol, acid)., Certain catalysts reach their maximum activity only when their constituent metals are in the form of sulfides (e.g., the hydrotreating catalysts used in oil refining). Preliminary treatment with hydrogen sulfide is sometimes necessary. However, hydrogen sulfide also poisons some hydrogenation and reforming catalysts with a platinum or palladium base. This can be used to advantage to reduce initial catalyst activity and limit coking (i.e., formation of carbonaceous deposits). Gasoline reforming catalysts, for example, are always selectively poisoned with a small quantity of hydrogen sulfide prior to use., Preliminary treatment with hydrogen sulfide is sometimes required for the purification of ore by selective flotation. ... This process is used in the purification of nickel and manganese., For more Uses (Complete) data for HYDROGEN SULFIDE (9 total), please visit the HSDB record page., Volcanoes and hot springs emit some hydrogen sulfide, where it probably arises via the hydrolysis of sulfide minerals. Hydrogen sulfide can be present naturally in well water, it can be removed using ozone or a filter with manganese dioxide. About 10% of total global emissions of H2S is due to human activity. By far the largest industrial route to hydrogen sulfide occurs in petroleum refineries. Other anthropogenic sources of hydrogen sulfide include coke ovens, paper mills, and tanneries. H2S arises from virtually anywhere where elemental sulfur comes into contact with organic material, especially at high temperatures. Being heavier than air, H2S tends to accumulate at the bottom of poorly ventilated spaces. (L1139), Use Classification: Chemical Classes -> Inorganic substances, Household Products: Information on 6 consumer products that contain Hydrogen sulfide in the following categories is provided:, • Home Maintenance, Methods of Manufacturing: Hydrogen sulfide is formed when hydrogen is fed into sulfur at 350 °C with or without a catalyst (e.g., bauxite, aluminum silicate, cobalt molybdate. High pressure also aids the reaction. ... In the industrial production of hydrogen sulfide (Fig. 1), the reaction occurs at 450 °C and 0.7 MPa. Hydrogen sulfide is separated from sulfur vapor by cooling and solidifying the sulfur on the walls of a heat exchanger. The exchanger is alternately cooled and heated to remelt and eliminate the sulfur deposit., Sulfur reacts with methane to form a mixture of hydrogen sulfide and carbon disulfide. Carbon disulfide can be hydrolyzed, giving additional hydrogen sulfide. With higher alkanes (>C10) having a low vapor pressure, reaction takes place at 200-300 °C., Hydrogen sulfide is obtained from ... gas: 1. directly if the hydrogen sulfide-carbon dioxide ratio is high enough to give an acid gas with the desired hydrogen sulfide content (80-90 vol%) or if a selective sweetening process is used, 2. after additional treatment, consisting of selective reprocessing (desired purity, 90-95%) or compression and subsequent distillation (minimum purity 99.5%)., Derivation: (1) By the action of dilute sulfuric acid on a sulfide, usually iron sulfide, (2) by direct union of hydrogen and sulfur vapor at a definite temperature and pressure, (3) as a by-product of petroleum refining., Natural gas, synthesis gas, refinery gas, coke oven gas (solvent extraction), hydrogen + sulfur (reaction), natural gas (Lacquer distillation process), natural gas + sulfur (reaction, by-product of carbon disulfide production), metallurgic coke + sulfur (reaction, coproduced with carbon disulfide)., Formulations, Preparations: Grade: Technical 98.5%, purified 99.5% min, CP, chemically pure, ., Consumption Patterns: 8.85X10+11 G AS AN INT FOR SULFURIC ACID (1966), U.S. Production: Production volumes for non-confidential chemicals reported under the Inventory Update Rule.[Table#1666], Production volume for non-confidential chemicals reported under the 2006 Inventory Update Rule. Chemical: Hydrogen sulfide. Aggregated National Production Volume: 1 billion lbs and greater., General Manufacturing Information: Hydrogen sulfide (H2S): ACTIVE.

Technical Profile

What this product is

Biodiesel is a chemical compound with CAS registry number 37331-50-3 and molecular formula H2S (molecular weight 34.08).

Identification

CAS number: 37331-50-3

Its molecular formula H2S comprises 2 H, 1 S atoms.

Also known as: Biodiesel · 生物柴油

Frequently Asked Questions

What is the CAS number of Biodiesel?

The CAS registry number of Biodiesel is 37331-50-3.

What is the molecular formula and molecular weight of Biodiesel?

Molecular formula H2S, molecular weight 34.08.

What other names is Biodiesel known by?

It is also registered under: Biodiesel, 生物柴油.

What are the documented applications of Biodiesel?

Recorded applications: Uses: Hydrogen sulfide is produced naturally by decaying organic matter and is released from sewage sludge, liquid manure, sulfur hot springs, and natural gas. It is a byproduct of many industrial processes including petroleum refining, tanning, mining, wood pulp processing, rayon manufacturing, sugar beet processing, and hot asphalt paving. Hydrogen sulfide is used to produce elemental sulfur, sulfuric acid, and heavy water for nuclear reactors. [ATSDR Medical Management], Steel Producing [Category: Industry], Petroleum Production and Refining [Category: Industry], Pulp and Paper Processing [Category: Industry], Textiles (Fiber & Fabric Manufacturing) [Category: Industry], Mining [Category: Industry], Sewer and Wastewater Treatment [Category: Industry], Leather Tanning and Processing [Category: Industry], Farming (Respiratory Hazards) [Category: Industry], Smoking cigarettes [Category: Food & Drugs], Superficial sulfurization of metals with hydrogen sulfide allows modification of their physical or chemical properties. Hydrogen sulfide is used for passivation of the walls of reactors operating at high temperature in petrochemical operations such as steam cracking and hydrodealkylation. This treatment prevents desirable secondary reactions. Another use of hydrogen sulfide is the formation of a layer of sulfide on the surface of steel wires or plates that are to be coated with paint or plastic. This treatment protects the coating or improves the action of adhesive primers., The most common industrial application of hydrogen sulfide is the production of organic compounds with a thiol function (i.e., RSH, where R is a hydrocarbon group) or a thiol group and another function (e.g., alcohol, acid)., Certain catalysts reach their maximum activity only when their constituent metals are in the form of sulfides (e.g., the hydrotreating catalysts used in oil refining). Preliminary treatment with hydrogen sulfide is sometimes necessary. However, hydrogen sulfide also poisons some hydrogenation and reforming catalysts with a platinum or palladium base. This can be used to advantage to reduce initial catalyst activity and limit coking (i.e., formation of carbonaceous deposits). Gasoline reforming catalysts, for example, are always selectively poisoned with a small quantity of hydrogen sulfide prior to use., Preliminary treatment with hydrogen sulfide is sometimes required for the purification of ore by selective flotation. ... This process is used in the purification of nickel and manganese., For more Uses (Complete) data for HYDROGEN SULFIDE (9 total), please visit the HSDB record page., Volcanoes and hot springs emit some hydrogen sulfide, where it probably arises via the hydrolysis of sulfide minerals. Hydrogen sulfide can be present naturally in well water, it can be removed using ozone or a filter with manganese dioxide. About 10% of total global emissions of H2S is due to human activity. By far the largest industrial route to hydrogen sulfide occurs in petroleum refineries. Other anthropogenic sources of hydrogen sulfide include coke ovens, paper mills, and tanneries. H2S arises from virtually anywhere where elemental sulfur comes into contact with organic material, especially at high temperatures. Being heavier than air, H2S tends to accumulate at the bottom of poorly ventilated spaces. (L1139), Use Classification: Chemical Classes -> Inorganic substances, Household Products: Information on 6 consumer products that contain Hydrogen sulfide in the following categories is provided:, • Home Maintenance, Methods of Manufacturing: Hydrogen sulfide is formed when hydrogen is fed into sulfur at 350 °C with or without a catalyst (e.g., bauxite, aluminum silicate, cobalt molybdate. High pressure also aids the reaction. ... In the industrial production of hydrogen sulfide (Fig. 1), the reaction occurs at 450 °C and 0.7 MPa. Hydrogen sulfide is separated from sulfur vapor by cooling and solidifying the sulfur on the walls of a heat exchanger. The exchanger is alternately cooled and heated to remelt and eliminate the sulfur deposit., Sulfur reacts with methane to form a mixture of hydrogen sulfide and carbon disulfide. Carbon disulfide can be hydrolyzed, giving additional hydrogen sulfide. With higher alkanes (>C10) having a low vapor pressure, reaction takes place at 200-300 °C., Hydrogen sulfide is obtained from ... gas: 1. directly if the hydrogen sulfide-carbon dioxide ratio is high enough to give an acid gas with the desired hydrogen sulfide content (80-90 vol%) or if a selective sweetening process is used, 2. after additional treatment, consisting of selective reprocessing (desired purity, 90-95%) or compression and subsequent distillation (minimum purity 99.5%)., Derivation: (1) By the action of dilute sulfuric acid on a sulfide, usually iron sulfide, (2) by direct union of hydrogen and sulfur vapor at a definite temperature and pressure, (3) as a by-product of petroleum refining., Natural gas, synthesis gas, refinery gas, coke oven gas (solvent extraction), hydrogen + sulfur (reaction), natural gas (Lacquer distillation process), natural gas + sulfur (reaction, by-product of carbon disulfide production), metallurgic coke + sulfur (reaction, coproduced with carbon disulfide)., Formulations, Preparations: Grade: Technical 98.5%, purified 99.5% min, CP, chemically pure, ., Consumption Patterns: 8.85X10+11 G AS AN INT FOR SULFURIC ACID (1966), U.S. Production: Production volumes for non-confidential chemicals reported under the Inventory Update Rule.[Table#1666], Production volume for non-confidential chemicals reported under the 2006 Inventory Update Rule. Chemical: Hydrogen sulfide. Aggregated National Production Volume: 1 billion lbs and greater., General Manufacturing Information: Hydrogen sulfide (H2S): ACTIVE.

PubChem Public Data

Independent reference data for Biodiesel (CAS 37331-50-3), compiled from public chemistry databases.

Registry identifiers across databases

CAS Registry Number37331-50-3
PubChem CID402
Molecular formulaH2S
IUPAC namesulfane
UNII (FDA)YY9FVM7NSN
FEMA number3779

Computed descriptors

Molecular Weight34.08
XLogP30.5
Hydrogen Bond Donor Count1
Hydrogen Bond Acceptor Count1
Rotatable Bond Count0
Exact Mass33.98772124
Monoisotopic Mass33.98772124
Topological Polar Surface Area1
Heavy Atom Count1

Physicochemical values on record

Boiling Point-76.59 °F at 760 mmHg (EPA, 1998)
Boiling Point-60.33 °C
Boiling Point-60 °C
Boiling Point-76.59 °F
Boiling Point-59.55 °C @760 [mm Hg]
Boiling Point-77 °F
Melting Point-121.9 °F (EPA, 1998)
Melting Point-85.49 °C
Melting Point-85 °C
Melting Point-121.88 °F

Documented uses on record

    Hydrogen sulfide is produced naturally by decaying organic matter and is released from sewage sludge, liquid manure, sulfur hot springs, and natural gas. It is a byproduct of many industrial processes including petroleum refining, tanning, mining, wood pulp processing, rayon manufacturing, sugar beet processing, and hot asphalt paving. Hydrogen sulfide is used to produce elemental sulfur, sulfuric acid, and heavy water for nuclear reactors. [ATSDR Medical Management]Steel Producing [Category: Industry]

    Synonyms and trade names

    hydrogen sulfide; Hydrosulfuric acid; Dihydrogen sulfide; Dihydrogen monosulfide; Stink DAMP; Hydrogen sulphide; Sulfureted hydrogen; 7783-06-4; Sewer gas; Hydrogene sulfure; Acide sulfhydrique; Schwefelwasserstoff; Zwavelwaterstof; Siarkowodor; Hydrogen-sulfide; Idrogeno solforato

    Regulatory listings held on file

    Regulatory & Food ContactEU Flavoring substances
    FDA Substance added to food: FLAVORING AGENT OR ADJUVANT
    Flavoring Agents

    GHS hazard classification

    Reported hazard statementsH220, H330, H400, H280 (27.1%), H319, H370

    H220: Extremely flammable gas [Danger Flammable gases]

    H330: Fatal if inhaled [Danger Acute toxicity, inhalation]

    What the public record says

    Biodiesel · CAS 37331-50-3 · H2S. UNII YY9FVM7NSN. Boiling Point: -76.59 °F at 760 mmHg (EPA, 1998); Boiling Point: -60.33 °C; Boiling Point: -60 °C.

    Physical description and handling notes

    Source: PubChem / Wikidata; the batch COA governs where values differ.

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